Front matter pg P001; DOI: 10.1039/P198400FP001 |
Optical rotatory dispersion and absolute configuration. Part 35. Chiroptical properties and conformation of indolizidine Bjorn Ringdahl A. Reginald Pinder Wilfred E. Pereira Jr. Norman J. Oppenheimer and John Cymerman Craig pg 1; DOI: 10.1039/P19840000001 |
Index pages pg A003; DOI: 10.1039/P198400BA003 |
Synthesis and stereochemical studies on the reductions of some pyrrole derivatives Sudin Bhattacharya Asok N. Mandal Swadesh R. Ray Chaudhuri and Amareshwar Chatterjee pg 5; DOI: 10.1039/P19840000005 |
Photoinduced electron transfer reaction. Part 3. 9,10-Dicyanoanthracene-sensitized photo-oxidation of electron-rich stilbene oxides Shigeru Futamura Shosaku Kusunose Hiroyuki Ohta and Yoshio Kamiya pg 15; DOI: 10.1039/P19840000015 |
Preparation and properties of substituted 6-vinylpenicillanic acids Christopher D. Foulds Albert A. Jaxa-Chamiec Anthony C. O'Sullivan and Peter G. Sammes pg 21; DOI: 10.1039/P19840000021 |
The synthesis of peptide -lactams as potential protease inhibitors Clifford J. Wharton Roger Wrigglesworth and Michael Rowe pg 29; DOI: 10.1039/P19840000029 |
XY–ZH systems as potential 1,3-dipoles. Part 1. Background and scope Ronald Grigg H. Q. Nimal Gunaratne and James Kemp pg 41; DOI: 10.1039/P19840000041 |
XY–ZH systems as potential 1,3-dipoles. Part 2. Oxime cycloadditions: formation of 2 : 1 adducts Ronald Grigg Maurice Jordan Aant Tangthongkum Frederick W. B. Einstein and Terry Jones pg 47; DOI: 10.1039/P19840000047 |
Bifunctional chelating agents. Part 2. Synthesis of 1-(2-carboxyethyl)ethylenediaminetetra-acetic acid by ring cleavage of a substituted imidazole Janina Altman Nurit Shoef Meir Wilchek and Abraham Warshawsky pg 59; DOI: 10.1039/P19840000059 |
Cyclic meso-ionic compounds. Part 21. The examination of nitro-derivatives of meso-ionic heterocycles as potential pharmaceuticals Christopher G. Newton W. David Ollis Michael L. Podmore and Derek E. Wright pg 63; DOI: 10.1039/P19840000063 |
Cyclic meso-ionic compounds. Part 22. Meso-ionic derivatives of the imidazo[1,2-a]pyridinium system and the unexpected synthesis of stable pyridinium dinitromethylides Christopher G. Newton W. David Ollis and Derek E. Wright pg 69; DOI: 10.1039/P19840000069 |
Cyclic meso-ionic compounds. Part 23. Novel chemistry of 1,2,4-thiadiazoles and their transformation into meso-ionic 1,2,4-thiadiazolium derivatives Christopher G. Newton W. David Ollis and Derek E. Wright pg 75; DOI: 10.1039/P19840000075 |
Synthesis and reactivity of sulphinyldithioacetate and sulphonyldithioacetate esters and some related compounds Masataka Yokoyama Koichi Tsuji Masahiro Hayashi and Tsuneo Imamoto pg 85; DOI: 10.1039/P19840000085 |
New route for synthesis of furan derivatives from protected -ketols and ketones. A total synthesis of furoventalene Hisahiro Hagiwara and Hisashi Uda pg 91; DOI: 10.1039/P19840000091 |
Dehydration of dimeric 6-hydroxycyclohexa-2,4-dienones–an alternative course for these reactions and a model for the maytenone to anhydromaytenone transformation Christopher P. Falshaw and Aristophanes Franklinos pg 95; DOI: 10.1039/P19840000095 |
Synthesis of 4- and 5-benzothiazol-2-yldithio-2,6-dimethylocta-2,6-diene and other models for pendent groups in the sulphur vulcanisation of natural rubber Norman J. Morrison pg 101; DOI: 10.1039/P19840000101 |
Silver nitrate–alumina: a chromatographic reaction medium for conversion of 5-halogenopent-2-enes into 1-cyclopropylethyl nitrate Robert T. Hrubiec and Michael B. Smith pg 107; DOI: 10.1039/P19840000107 |
The synthesis and chemistry of azolenines. Part 2. A general synthesis of pyrrole-2-carboxylic acid derivatives by the reaction of 2H-azirines with enamines, and the crystal and molecular structure of ethyl 3-phenyl-4,5,6,7-tetrahydroindole-2-carboxylate Kam Wah Law Ting-Fong Lai Michael P. Sammes Alan R. Katritzky and Thomas C. W. Mak pg 111; DOI: 10.1039/P19840000111 |
Stereospecific rearrangement of 2,2-disubstituted vinylsilane epoxides to the silyl enol ethers of 2,2-disubstituted aldehydes Ian Fleming and Trevor W. Newton pg 119; DOI: 10.1039/P19840000119 |
Metalloporphyrins in coal. 1. Gallium porphyrins in bituminous coals Raymond Bonnett and Franciszek Czechowski pg 125; DOI: 10.1039/P19840000125 |
Synthesis and reactivity of 2-oxidodiaryliodonium zwitterions Spyros Spyroudis and Anastasios Varvoglis pg 135; DOI: 10.1039/P19840000135 |
Stereoselective synthesis of plant growth-prompting steroids, brassinolide, castasterone, typhasterol, and their 28-nor analogues Suguru Takatsuto Naoto Yazawa Masaji Ishiguro Masuo Morisaki and Nobuo Ikekawa pg 139; DOI: 10.1039/P19840000139 |
2-(N,N-disubstituted amino)thiazoles with electron-withdrawing groups at position 5: preparation and investigation of structural features Timothy N. Birkinshaw David W. Gillon Shaun A. Harkin G. Denis Meakins and Malcom D. Tirel pg 147; DOI: 10.1039/P19840000147 |
The design and synthesis of new triazolo, pyrazolo-, and pyridazo-pyridazine derivatives as inhibitors of angiotensin converting enzyme Cedric H. Hassall Antonin Kröhn Christopher J. Moody and W. Anthony Thomas pg 155; DOI: 10.1039/P19840000155 |
Tricyclic [10]annulenes. Part 2. Synthesis of 7b-methyl-7bH-cyclopent[cd]indene Raymond McCague Christopher J. Moody and Charles W. Rees pg 165; DOI: 10.1039/P19840000165 |
Tricyclic [10]annulenes. Part 3. Reactions of 7b-methyl-7bH-cyclopent[cd]indene Raymond McCague Christopher J. Moody and Charles W. Rees pg 175; DOI: 10.1039/P19840000175 |
Total synthesis of parabactin, a spermidine siderophore Yoshimitsu Nagao Tadayo Miyasaka Yuichi Hagiwara and Eiichi Fujita pg 183; DOI: 10.1039/P19840000183 |
Asymmetric synthesis of protected -hydroxyaldehydes via reduction of -arylthio--oxosulphoxides Giuseppe Guanti Enrica Narisano Francesca Pero Luca Banfi and Carlo Scolastico pg 189; DOI: 10.1039/P19840000189 |
Conversion of alcohols into alkyl bromides using polymer-supported triphenylphosphine dibromide and polymer-supported triphenylphosphine and carbon tetrabromide Philip Hodge and Ezzatollah Khoshdel pg 195; DOI: 10.1039/P19840000195 |
New functionalized cycloheptatrienes via tropone -adducts Marino Cavazza Gioia Morganti Antonio Guerriero and Francesco Pietra pg 199; DOI: 10.1039/P19840000199 |
Structures and conformations of (–)-isobicyclogermacrenal and (–)-lepidozenal, two key sesquiterpenoids of the cis- and trans-10,3-bicyclic ring systems, from the liverwort Lepidozia vitrea : X-ray crystal structure analysis of the hydroxy derivative of (–)-isobicyclogermacrenal Akihiko Matsuo Hirshi Nozaki Naoji Kubota Seiryo Uto and Mitsuru Nakayama pg 203; DOI: 10.1039/P19840000203 |
Structure and absolute configuration of (+)-vitrenal, a novel carbon skeletal sesquiterpenoid having plant-growth-inhibitory activity, from the liverwort Lepidozia vitrea Akihiko Matsuo Seiryo Uto Hirshi Nozaki and Mitsuru Nakayama pg 215; DOI: 10.1039/P19840000215 |
Electrocyclic aromatic substitution by the diazo group. Part 4. Periselectivity studies on the cyclisation of 1-thienyl-3-diazoalkenes: a route to 3H-thieno[1,2]diazepines Thomas K. Miller and John T. Sharp pg 223; DOI: 10.1039/P19840000223 |
Synthesis of imidazo-fused bridgehead-nitrogen C-nucleosides via dehydrative coupling reactions of 2,5-anhydro-3,4,6-tri-O-benzoyl-D-allonic acid Lars J. S. Knutsen Brian D. Judkins William L. Mitchell Roger F. Newton and David I. C. Scopes pg 229; DOI: 10.1039/P19840000229 |
Photochemical ring opening of pyrimidin-2(1H)-ones. Part 2. Takehiko Nishio and Yoshimori Omote pg 239; DOI: 10.1039/P19840000239 |
Diastereoselectivity in the Horner-Wittig reaction: X-ray crystal structure of 2-(1RS,2SR)-diphenylphosphinoyl-1-phenylpropan-1-ol Anthony D. Buss William B. Cruse Olga Kennard and Stuart Warren pg 243; DOI: 10.1039/P19840000243 |
3H-azepines and related systems. Part 2. The photolyses of aryl azides bearing electron-withdrawing substituents Roger Purvis Robert K. Smalley Hans Suschitzky and Mohamed A. Alkhader pg 249; DOI: 10.1039/P19840000249 |
Intramolecular cyclisation using methyl(bismethylthio)sulphonium salts, bromine, and iodine. 5-Methylene-4,5-dihydro-oxazoles from 3-amidopropynes Giuseppe Capozzi Corrado Caristi and Mario Gattuso pg 255; DOI: 10.1039/P19840000255 |
Regioselectivity in the intramolecular carbon–hydrogen insertion in metal-catalysed decomposition of some cis-1-methyl-3-arylcyclohexyl diazomethyl ketones. A highly efficient homogeneous nickel catalyst for carbenoid insertion Asit K. Chakraborti Jayanta K. Ray Kalyan K. Kundu Sephali Chakrabarty Debabrata Mukherjee and Usha Ranjan Ghatak pg 261; DOI: 10.1039/P19840000261 |
Chemistry of bacterial endotoxins. Part 1. Block synthesis of 6-O-{4-O-ammonio(hydrogen)phosphono-2-deoxy-2-[(3R)-3-hydroxy-tetradecanamido]--D-glucopyranosyl}-2-deoxy-2-[(3R)-3-hydroxy-tetradecanamido]-D-glucose Christian Diolez Michelle Mondange S. Robert Sarfati Ladislas Szabó and Patricia Szabó pg 275; DOI: 10.1039/P19840000275 |
Succinimidation by N-bromosuccinimide of N,N-dimethylamido and N,N-dimethylamino groups Corrado Caristi Alida Ferlazzo and Mario Gattuso pg 281; DOI: 10.1039/P19840000281 |
Reactions between enaminones and enones. Part 2. Alkylation of enaminones with acrylic esters John V. Greenhill M. Ashraf Moten and Reiner Hanke pg 287; DOI: 10.1039/P19840000287 |
Lewis acid catalysis of the ene addition of chloral and bromal to olefins; product studies Jill P. Benner G. Bryon Gill Stephen J. Parrott and Brian Wallace pg 291; DOI: 10.1039/P19840000291 |
Lewis acid catalysis of the ene addition of chloral and bromal to olefins; stereochemical and mechanistic studies Jill P. Benner G. Bryon Gill Stephen J. Parrott Brian Wallace and Michael J. Begley pg 315; DOI: 10.1039/P19840000315 |
Some aspects of the chemistry of 1,1,1-trihalogenoalk-4-en-2-ols, the ene adducts obtained from reaction of chloral and bromal with alkenes Jill P. Benner G. Bryon Gill Stephen J. Parrott and Brian Wallace pg 331; DOI: 10.1039/P19840000331 |
Synthesis of condensed tannins. Part 12. Direct access to [4,6]- and [4,8]-all-2,3-cis-procyanidin derivatives from (–)-epicatechin : assessment of bonding positions in oligomeric analogues from Crataegus oxyacantha L. Herbert Kolodziej Daneel Ferreira and David G. Roux pg 343; DOI: 10.1039/P19840000343 |
N.m.r. assignments of ring A hydrogens in gibberellin A4 methyl esters and some derivatives Jake MacMillan and Christine L. Willis pg 351; DOI: 10.1039/P19840000351 |
Stereoselective deuteriation at carbon 2 of the gibberellins Jake MacMillan and Christine L. Willis pg 357; DOI: 10.1039/P19840000357 |
The stereochemistry of reduction of A gibberellin 1-unsaturated ketone Zvitendo J. Duri and James R. Hanson pg 363; DOI: 10.1039/P19840000363 |
o-Nitroaniline derivatives. Part 8. Synthesis of some unsymmetrical dimethylquinoxalines: a long-standing problem resolved David C. W. Blaikley David W. Currie David W. Smith Susan A. Watson and Hamish McNab pg 367; DOI: 10.1039/P19840000367 |
The thermolysis of polyazapentadienes. Part 3. Cyclisation of C-methyl-1,2,5-triazapentadienes and related compounds: the role of an intermediate spirodienyl radical Hamish McNab pg 371; DOI: 10.1039/P19840000371 |
The thermolysis of polyazapentadienes. Part 4. Formation of indoles and quinoxalines from 5-(2,6-disubstituted phenyl)-1,2,5-triazapentadienes and related compounds Hamish McNab pg 377; DOI: 10.1039/P19840000377 |
The thermolysis of polyazapentadienes. Part 5. Degenerate rearrangement of aryliminoiminyl radicals: a 15N-labelling study Hamish McNab and Graeme S. Smith pg 381; DOI: 10.1039/P19840000381 |
7-Substituted benzo[b]thiophenes and 1,2-benzisothiazoles. Part 2. Chloro and nitro derivatives Loay K. A. Rahman and Richard M. Scrowston pg 385; DOI: 10.1039/P19840000385 |
Photochemical reactions of pyrazin-2(1H)-ones Takehiko Nishio Naoko Nakajima Masaji Kondo Yoshimori Omote and Menahem Kaftory pg 391; DOI: 10.1039/P19840000391 |
Pentacyclic steroids. Part 1. Synthesis and X-ray conformational analysis of 4,5- and 4,5-dihydrobenzo[4,5,6]cholestan-5(6H)-one James R. Bull Lynne M. Steer and Petrus H. van Rooyen pg 397; DOI: 10.1039/P19840000397 |
Regio- and stereo-chemical aspects of [2 + 2] photocycloaddition between 1-benzoylindoles and olefins Masazumi Ikeda Kazunori Ohno Shin-ichiro Mohri Masami Takahashi and Yasumitsu Tamura pg 405; DOI: 10.1039/P19840000405 |
Importance of the C(3) substituent of the penam derivative in interconversion reactions of penam and cepham systems Aldo Balsamo Paola Maria Benedini Bruno Macchia Franco Macchia and Armando Rossello pg 413; DOI: 10.1039/P19840000413 |
Sucrochemistry. Part 33. The selective pivaloylation of sucrose Manjit S. Chowdhary Leslie Hough and Anthony C. Richardson pg 419; DOI: 10.1039/P19840000419 |
The pyrolysis of 2-azidobenzoates. A new synthesis of carbazoles and other N-heterocycles Michael G. Clancy Massoud M. Hesabi and Otto Meth-Cohn pg 429; DOI: 10.1039/P19840000429 |
Chloro(phenylthio)methyltrimethylsilane: preparation and some synthetic reactions Iwao Yamamoto Kazuhide Okuda Shigemasa Nagai Jiro Motoyoshiya Haruo Gotoh and Kei Matsuzaki pg 435; DOI: 10.1039/P19840000435 |
Synthesis and activity of plant growth-promoting steroids, (22R,23R,24S)-28-homobrassinosteroids, with modifications in rings A and B Suguru Takatsuto and Nobuo Ikekawa pg 439; DOI: 10.1039/P19840000439 |
Stereocontrolled synthesis of withanolide D and related compounds Keiji Gamoh Masao Hirayama and Nobuo Ikekawa pg 449; DOI: 10.1039/P19840000449 |
Reactions of polyfluorocyclohexane- and polyfluorocyclohexene-carbonitriles Gurjeet S. Phull Raymond G. Plevey and John Colin Tatlow pg 455; DOI: 10.1039/P19840000455 |
The action of sodium nitrite–acetic acid on - and -pinene. Participation by a neighbouring geminal dinitro group in the base-catalysed epimerization of a secondary alcohol Cosme G. Franisco Raimundo Freire Rosendo Hernández Daniel Melián José A. Salazar and Ernesto Suárez pg 459; DOI: 10.1039/P19840000459 |
Studies on Indian medicinal plants. Part 77. Structure and stereochemistry of some new steroidal alkaloids from Solanum pseudocapsicum and Solanum giganteum by nuclear magnetic resonance spectroscopy Ajit K. Chakravarty Binayak Das Esahak Ali and Satyesh C. Pakrashi pg 467; DOI: 10.1039/P19840000467 |
Resolution of -methyl and -fluoroglutamic acids. Lack of stereospecificity of leucine aminopeptidase with L-leucyl-L-erthro--substituted glutamates Sonia Bory Joëlle Dubois Michel Gaudry Andrée Marquet Liliane Lacombe and Shulamith Weinstein pg 475; DOI: 10.1039/P19840000475 |
2,5-Dilithiation of N-protected imidazoles. Syntheses of 2,5-disubstituted derivatives of 1-methoxymethyl-, 1-triphenylmethyl-, and 1-(N,N-dimethylsulphonamido)-imidazole Derek J. Chadwick and Raphael I. Ngochindo pg 481; DOI: 10.1039/P19840000481 |
Some reactions of carbenoids with chromone-2-carboxylic esters Ian D. Dicker John Shipman and John L. Suschitzky pg 487; DOI: 10.1039/P19840000487 |
Asymmetric syntheses. Part 11. Reduction of ketones and related ketone oximes with lithium aluminium hydride–3-O-cyclohexylmethyl-1,2-O-cyclohexylidene--D-glucofuranose complex to give optically active alcohols and amines Stephen. R. Landor Yuet M. Chan Olutunji O. Sonola and Austin R. Tatchell pg 493; DOI: 10.1039/P19840000493 |
New metabolic products of Verticillium lecanii. Part 1. 3-Hydroxy-4,4,14-trimethyl-5-pregna-7,9(11)-diene-20S-carboxylic acid and the isolation and characterisation of some minor metabolites Norman Claydon John Frederick Grove Michael Pople and Michael J. Begley pg 497; DOI: 10.1039/P19840000497 |
Studies of the syntheses of heterocyclic compounds containing benzopyrone. Part 3. Synthesis of 2-methyl-4H,5H-pyrano[3,2-c][1]benzopyran-4-one, the basic skeleton in citromycetin Masashige Yamauchi Sadamu Katayama Yoshihiko Nakashita and Toshio Watanabe pg 503; DOI: 10.1039/P19840000503 |
Polyhalogenoheterocyclic compounds. Part 36. Additions of diazomethane to perfluoropolyalkylethenes. A frontier orbital rationalisation of reactions of fluorinated alkenes with 1,3-dipoles and nucleophiles Martin R. Bryce Richard D. Chambers and Graham Taylor pg 509; DOI: 10.1039/P19840000509 |
Thermal reactions of 2-alkyl (or aryl)-1-benzoyl-3,4-dihydro-1H-2-thionianaphthalen-1-ides with compounds possessing an acidic hydrogen Tadashi Kataoka Akihiko Tomoto Hiroshi Shimizu Eiji Imai and Mikio Hori pg 515; DOI: 10.1039/P19840000515 |
Regioselective cleavage of the dithiolane S–S bond of ()--lipoic acid by carbon and phosphorus nucleophiles Edward H. Smith pg 523; DOI: 10.1039/P19840000523 |
Photochemical alkylamination of 1-acylaminoanthraquinones Katsuhira Yoshida Tetsuo Okugawa Eiichi Nagamatsu Yoshio Yamashita and Masaru Matsuoka pg 529; DOI: 10.1039/P19840000529 |
Novel routes to furan-3(2H)-ones. New syntheses of bullatenone and geiparvarin Richard F. W. Jackson and Ralph A. Raphael pg 535; DOI: 10.1039/P19840000535 |
The synthesis of 2,2-dialkylgibberellins Michael H. Beale Jake MacMillan Clive R. Spray David A. Taylor and Bernard O. Phinney pg 541; DOI: 10.1039/P19840000541 |
Hydrogen bonds involving polar CH groups. Part 11. Further confirmation of intramolecular bonds to nitrogen in 2-aminoalkyl-1,3-dithiane 1,1,3,3-tetraoxides by X-ray crystal structure analysis Richard L. Harlow Chuen Li and Michael P. Sammes pg 547; DOI: 10.1039/P19840000547 |
Synthesis of pyrazofurin and its analogues Nobuya Karagiri Kenichi Takashima Toru Haneda and Tetsuzo Kato pg 553; DOI: 10.1039/P19840000553 |
A new, general, and convenient synthesis of 5-deazaflavins (5-deazaisoalloxazines) and bis-(5-deazaflavin-10-yl)alkanes Tomohisa Nagamatsu Yuko Hashiguchi and Fumio Yoneda pg 561; DOI: 10.1039/P19840000561 |
The structure and biosynthesis of hinnuliquinone, a pigment from Nodulisporium hinnuleum Margaret A. O'Leary James R. Hanson and Boon Leng Yeoh pg 567; DOI: 10.1039/P19840000567 |
Electrocyclic aromatic substitution by the diazo group. Part 5. The reactions of -(2-arylthienyl)diazoalkanes David P. Munro and John T. Sharp pg 571; DOI: 10.1039/P19840000571 |
Photo-induced transformations. Part 69. The formation of bridged oxabicyclic compounds by intramolecular radical addition of oxyl radicals generated from B-homocholest-5-en-7a-ol hypoiodites Hiroshi Suginome Toshiharu Ohtsuka Kazuhiko Orito Carlos Jaime and Eiji sawa pg 575; DOI: 10.1039/P19840000575 |
Pyrimidine derivatives and related compounds. Part 47. A new synthesis of xanthines and pyrrolo[3,2-d]pyrimidines by intramolecular cyclisation of 6-substituted 5-nitrouracil derivatives Kosaku Hirota Tadashi Sugiyama Yukio Kitade Shigeo Senda and Yoshifumi Maki pg 583; DOI: 10.1039/P19840000583 |
Conversion of pimaric acid into cleistanthane derivatives Paolo Ceccherelli Massimo Curini Rita Coccia and Nera Cagnoli pg 589; DOI: 10.1039/P19840000589 |
Reaction of 2-methyl-1,4-naphthoquinone and its 3-substituted derivatives with active methylene group anions and with diazo compounds Peter H. Boyle Mary J. O'Mahony and Christine J. Cardin pg 593; DOI: 10.1039/P19840000593 |
Substitution reactions of the 3-epimeric methanesulphonates of methyl gibberellate Zvitendo J. Duri and James R. Hanson pg 603; DOI: 10.1039/P19840000603 |
Chemistry of amine–boranes. Part 10. Synthesis of sulphides from dithioacetals using pyridine–borane in acid Yasuo Kikugawa pg 609; DOI: 10.1039/P19840000609 |
Synthesis of hydrazone derivatives by reaction of azines with nitriles, and their transformation into pyrazoles and pyrimidones José Barluenga Laudina Muñiz Ma José Iglesias and Vicente Gotor pg 611; DOI: 10.1039/P19840000611 |
Synthesis of 1-vinylmenth-4(8)-ene, the purported sesquiterpene from Mentha citrata Tse-Lok Ho and Shing-Hou Liu pg 615; DOI: 10.1039/P19840000615 |
Hydroxyiminoisoquinolin-3(2H)-ones. Part 4. Synthesis and reactions of isoquinoline-3,4-diones István Tikk Gyula Deák Gábor Tóth and József Tamás pg 619; DOI: 10.1039/P19840000619 |
Thermal reaction of arylnitrenes with dimethyl sulphide, thioanisole, and tetrahydrothiophene Luisa Benati P. Carlo Montevecchi and Piero Spagnolo pg 625; DOI: 10.1039/P19840000625 |
Alkoxymercuriation of conjugated dienes. Regio- and stereo-selective synthesis of unsaturated diethers José Barluenga Julia Pérez-Prieto and Gregorio Asensio pg 629; DOI: 10.1039/P19840000629 |
Clavulanic acid and its derivatives. Structure elucidation of clavulanic acid and the preparation of dihydroclavulanic acid, isoclavulanic acid, esters and related oxidation products Allan G. Brown David F. Corbett Jennifer Goodacre John B. Harbridge T. Trefor Howarth Roger J. Ponsford Irene Stirling and (the late) Trevor J. King pg 635; DOI: 10.1039/P19840000635 |
Stereochemistry of bisbenzylisoquinoline N-oxides. Calafatine 2-N-oxide and calafatine 2-N-oxide John E. Leet Alan J. Freyer Robert D. Minard Maurice Shamma and Victor Fajardo pg 651; DOI: 10.1039/P19840000651 |
XY–ZH systems as potential 1,3-dipoles. Part 3. Isoxazolidines from the 1:1 cycloaddition of oximes with dipolarophiles Ronald Grigg and Sunit Thianpantangul pg 653; DOI: 10.1039/P19840000653 |
The preparation and utility of ethyl 2-(5-O-t-butyldimethylsilyl-2,3-O-isopropylidene--D-ribofuranosyl)propenoate as a key intermediate for C-nucleoside synthesis Peter D. Kane and John Mann pg 657; DOI: 10.1039/P19840000657 |
Saponins from roots of Platycodon grandiflorum. Part 2. Isolation and structure of new triterpene glycosides Hiroshi Ishii Kazuo Tori Takehiko Tozyo and Yohko Yoshimura pg 661; DOI: 10.1039/P19840000661 |
Chiral mono-, di-, and tri-chloromethylphosphonates and phosphonothioates: preparation, absolute configuration, and the stereochemical course of their reaction with methoxide C. Richard Hall Thomas D. Inch Gary Peacock Colin Pottage and Nancy E. Williams pg 669; DOI: 10.1039/P19840000669 |
Synthesis of ()-prostaglandin I2 methyl ester and its 15-epimer from 2-(cyclopent-2-enyl)-1-(2-oxocyclopentyl)ethanol derivatives Anthony D. Baxter Stanley M. Roberts Basil J. Wakefield Geoffrey T. Woolley and Roger F. Newton pg 675; DOI: 10.1039/P19840000675 |
Oxo complexes of ruthenium(VI) and (VII) as organic oxidants Graham Green William P. Griffith David M. Hollinshead Steven V. Ley and Martin Schröder pg 681; DOI: 10.1039/P19840000681 |
Synthesis of substituted indans as prostacyclin analogues Memnon Phialas Peter G. Sammes Peter D. Kennewell and Robert Westwood pg 687; DOI: 10.1039/P19840000687 |
Structure elucidation of the janthitrems, novel tremorgenic mycotoxins from Penicillium janthinellum Amelia E. de Jesus Pieter S. Steyn Fanie R. van Heerden and Robert Vleggaar pg 697; DOI: 10.1039/P19840000697 |
Substituted thian-4-ones. Part 3. Synthesis and reactions of 2-alkyl-5,6-dihydrothiin-4-ones Vinod K. Kansal and Richard J. K. Taylor pg 703; DOI: 10.1039/P19840000703 |
Synthesis of the yeast antioxidant benzofuran and analogues Brian A. McKittrick and Robert Stevenson pg 709; DOI: 10.1039/P19840000709 |
An expeditious synthesis of 4-alkoxycarbonyl-5-hydroxy-1,2,3-triazoles: the crystal and molecular structure of the 2-thienylammonium salt of 5-hydroxy-4-methoxycarbonyl-1-(2-thienyl)-1,2,3-triazole Peter Murray-Rust James McManus Sean P. Lennon Alexander E. A. Porter and Josef A. Rechka pg 713; DOI: 10.1039/P19840000713 |
Reductive aminations of ketones and aldehydes using borane–pyridine Andrew Pelter Richard M. Rosser and Stuart Mills pg 717; DOI: 10.1039/P19840000717 |
Sulphonamidomercuriation of olefins and subsequent reductive demercuriation or bromodemercuriation José Barluenga Carmen Jiménez Carmen Nájera and Miguel Yus pg 721; DOI: 10.1039/P19840000721 |
Reactions of 2-fluorotropone with Grignard reagents Marino Cavazza Gioia Morganti and Francesco Pietra pg 727; DOI: 10.1039/P19840000727 |
Cannabis. Part 29. Synthesis of four benzofuro[6,7-c][2]benzopyrans related to cannabinol Jirí Novák and Cornells A. Salemink pg 729; DOI: 10.1039/P19840000729 |
Synthesis of 3-amino-3,4-dideoxysugars Peter M. Collins W. George Overend and Veronica M. Racz pg 733; DOI: 10.1039/P19840000733 |
Reactions of 3-phenylthiobut-3-en-2-one. Part 4. Novel and efficient synthesis of 7-hydroxycalamenene, ferruginol, and D-homoestrone Ken Takaki Masakatsu Ohsugi Michikazu Okada Masateru Yasumura and Kenji Negoro pg 741; DOI: 10.1039/P19840000741 |
Observation on the synthesis of allenes by homologation of alk-1-ynes Scott Searles Yushun Li Bahman Nassim Maria-Teresa Robert Lopes P. T. Tran and Pierre Crabbé pg 747; DOI: 10.1039/P19840000747 |
Synthesis of bridged benzodiazepines by reaction of amines and hydrazine derivatives with 4,6-dibromormethyl-5,2,8-ethanylylidene-5H-1,9-benzodiazacycloundecine John M. Mellor and Ranjith N. Pathirana pg 753; DOI: 10.1039/P19840000753 |
Synthesis of benzodiaza[14]annulenes from 4,6-dibromomethyl-5,2,8-ethanylylidene-5H-1,9-benzodiazacycloundecine John M. Mellor and Ranjith N. Pathirana pg 761; DOI: 10.1039/P19840000761 |
Temperature dependence in the sensitized photoreaction of 3,3-dimethyloxepin-2(3H)-one and 2,2,7,7-tetramethylcyclohepta-3,5-dien-1-one Nobuto Hoshi Hisashi Uda Kazuhiro Sato and Hisahiro Hagiwara pg 769; DOI: 10.1039/P19840000769 |
The configurational stability of vinyl carbanions derived from monosubstituted activated ethylenes Ben-Ami Feit Uri Melamed Heike Speer and Richard R. Schmidt pg 775; DOI: 10.1039/P19840000775 |
Base-promoted reactions of -enaminones with 2-bromo-2-methylpropanamides. Formation of 2-ketonyloxazolidin-4-ones and cyclohexanespiro-oxazolidin-4-ones Augusto C. Veronese Paolo Scrimin Giorgio Vecchiati Stella Sferra and Ferruccio D'Angeli pg 781; DOI: 10.1039/P19840000781 |
Studies on amino acids and peptides. Part 6. Methods for introducing thioamide bonds into the peptide backbone: synthesis of the four monothio analogues of leucine enkephalin Kim Clausen Michael Thorsen Sven-Olov Lawesson and Arno F. Spatola pg 785; DOI: 10.1039/P19840000785 |
Bicyclo[3.3.0]octenones in synthesis. An approach to the synthesis of the antitumor sesquiterpene quadrone Kelvin Cooper and Gerald Pattenden pg 799; DOI: 10.1039/P19840000799 |
Bicyclo[3.3.0]octenones in synthesis. A new synthesis of ()-cedrene using sequential inter- and intra-molecular Michael reactions Michael Horton and Gerald Pattenden pg 811; DOI: 10.1039/P19840000811 |
Germacranolides of Erlangea cordifolia. Isolation and structures of cordifolia-54, -55, -P2, and -31 by spectral and X-ray methods Michael J. Begley Leslie Crombie W. Mary L. Crombie Ambrose K. Gatuma and Asafu Maradufu pg 819; DOI: 10.1039/P19840000819 |
Biosynthesis of phenanthroindolizidine alkaloids: incorporation of 2-pyrrolidin-2-ylacetophenone and benzoylacetic acid and derivatives Richard B. Herbert Frederick B. Jackson and Ian T. Nicolson pg 825; DOI: 10.1039/P19840000825 |
Electrochemical oxidation of aromatic ethers. Part 9. Proof of the mode of aryl–aryl coupling in 4-benzylisochroman-3-ones, and the oxidative reactions of 2-and 3-aralkyl-1,2,3,4-tetrahydroisoquinolines Amera J. Majeed Malcolm Sainsbury and Stephen A. Hall pg 833; DOI: 10.1039/P19840000833 |
Synthesis and spontaneous racemization of benz[a]anthracene 1,2-oxide Derek R. Boyd and Narain D. Sharma pg 839; DOI: 10.1039/P19840000839 |
Synthesis of 2,5- and 2,6-norbornane derivatives with prostaglandin-like side chains David I. Davies Peter M. Gomez and Peter Hallett pg 843; DOI: 10.1039/P19840000843 |
1,7-Electrocyclisation and carbene reactions of o-alkenylaryldiazoalkanes: the effect of alkene configuration on the mode of reaction David P. Munro and John T. Sharp pg 849; DOI: 10.1039/P19840000849 |
Preparation and cycloaddition reactions of some -unsaturated dithioesters Kevin R. Lawson Alison Singleton and Gordon H. Whitham pg 859; DOI: 10.1039/P19840000859 |
Addition of methyl but-2-enedithioate to cyclopentadiene. Cyclopentadiene as a dienophile Kevin R. Lawson Alison Singleton and Gordon H. Whitham pg 865; DOI: 10.1039/P19840000865 |
Biosynthesis of (25S)- and (25R)-furostanol glycosides from [1,2-13C2] acetate in Dioscorea tokoro tissue cultures Shujiro Seo Atsuko Uomori Yohko Yoshimura and Kazuo Tori pg 869; DOI: 10.1039/P19840000869 |
Unusual stereochemistry in the copper-catalysed ring opening of a carbohydrate oxirane with vinylmagnesium bromide Carol Brockway Philip Kocienski and Chandra Pant pg 875; DOI: 10.1039/P19840000875 |
Specificity of the 1-methyladenine receptors in starfish oocytes: synthesis and properties of some 1,8-disubstituted adenines, 1,6-dimethyl-1H-purine, and of the 1-(azidobenzyl)adenines René Mornet Nelson J. Leonard Jane B. Theiler and Marcel Doree pg 879; DOI: 10.1039/P19840000879 |
Studies of chrysanthemic acid derivatives: catalysed reactions of 3-(2-hydroxy-methyl-3,3-dimethylcyclopropyl)-2-methylpropanol and formation of a novel eight-membered cyclic sulphite Bernard Crammer Zeev Goldschmidt Raphael Ikan and Shmuel Cohen pg 887; DOI: 10.1039/P19840000887 |
Photochemical bromination of simple arenes Roger Bolton Muhammad Iqbal Bhangar and Gareth H. Williams pg 893; DOI: 10.1039/P19840000893 |
The triethylamine catalyzed reaction of N,N-disubstituted thioamide–bromine adducts with unsubstituted thiobenzamide Antonino Corsaro Anna Compagnini Giancarlo Perrini and Giovanni Purrello pg 897; DOI: 10.1039/P19840000897 |
Generation and Diels–Alder reactions of 3-acyl-3-pyrroline-2,5-diones Michael L. Durrant and Eric J. Thomas pg 901; DOI: 10.1039/P19840000901 |
Enantiospecific synthesis of shikimic acid from D-mannose: formation of a chiral cyclohexene by intramolecular olefination of a carbohydrate-derived intermediate George W. J. Fleet Tony K. M. Shing and Steven M. Warr pg 905; DOI: 10.1039/P19840000905 |
Tricyclic [10]annulenes. Part 4. The effect of benzo-fusion: synthesis, properties, and X-ray structure of 9c-methyl-9cH-cyclopenta[jk]fluorene Raymond McCague Christopher J. Moody Charles W. Rees and David J. Williams pg 909; DOI: 10.1039/P19840000909 |
Ring cleavage of a 3-azidothiophene: novel extrusion of acetylene Christopher J. Moody Charles W. Rees and Siu Chung Tsoi pg 915; DOI: 10.1039/P19840000915 |
Polarised ketene dithioacetals. Part 32. Studies on base-catalysed rearrangements of 2-bis(methylthio)methyleneindan-1-one, 2-bis(methylthio)methylene-1-tetralone, and 3-bis(methylthio)methylene-2,3-dihydro-1-benzothiopyran-4-one Satyam Apparao Apurba Datta Hiriyakkanavar Ila and Hiriyakkanavar Junjappa pg 921; DOI: 10.1039/P19840000921 |
Reactions of co-ordinated ligands. Part 10. Rhodium-catalysed cyclisation of 3-(2-fluorophenyl)propanols to chromans Roy P. Houghton Martyn Voyle and Raymond Price pg 925; DOI: 10.1039/P19840000925 |
Palladium on charcoal-catalysed arylation of methyl vinyl ether with 4-bromonitrobenzene Anders Hallberg and Lars Westfelt pg 933; DOI: 10.1039/P19840000933 |
Stemonolone, a new sesquiterpenoid from Pogostemon plectranthoides(Desf) Anil P. Phadnis Sarita A. Patwardhan Amrit S. Gupta Kunjibettu R. Acharya Sudam S. Tavale and Tayur N. Guru Row pg 937; DOI: 10.1039/P19840000937 |
Reactions of pyridinium ylides with aldehydes and with Michael acceptors Alan R. Katritzky Olga Rubio Jose M. Aurrecoechea and Ranjan C. Patel pg 941; DOI: 10.1039/P19840000941 |
The synthesis and chemistry of azolenines. Part 3. Some reactions of 4H-pyrazole quaternary salts Alan R. Katritzky Jamshed N. Lam Olga Rubio and Michael P. Sammes pg 947; DOI: 10.1039/P19840000947 |
Specific enzyme inhibitors in vitamin biosynthesis. Part 5. Purification of riboflavin synthase by affinity chromatography using 7-oxolumazines Colin D. Ginger Roger Wrigglesworth W. David Inglis Russel J. Kulick Colin J. Suckling and Hamish C. S. Wood pg 953; DOI: 10.1039/P19840000953 |
Specific enzyme inhibitors in vitamin biosynthesis. Part 6. Identification of an affinity chromatography ligand for the purification of riboflavin synthase Roger Wrigglesworth W. David Inglis Daniel B. Livingstone Colin J. Suckling and Hamish C. S. Wood pg 959; DOI: 10.1039/P19840000959 |
The structure of cotyledoside, a novel toxic bufadienolide glycoside from Tylecodon wallichii(Harv.) Toelken Pieter S. Steyn Fanie R. van Heerden and Andre J. van Wyk pg 965; DOI: 10.1039/P19840000965 |
Transition-metal-catalysed Grignard reaction of secondary allylic phosphates Shuki Araki and Yasuo Butsugan pg 969; DOI: 10.1039/P19840000969 |
Electro-organic reactions. Part 24. Preparative and mechanistic aspects of the anodic oxidation of dithioacetals and 1,3-dithianes Quentin N. Porter James H. P. Utley Pedro D. Machion Vera L. Pardini Paulo R. Schumacher and Hans Viertler pg 973; DOI: 10.1039/P19840000973 |
Electrophilic aromatic N-substitution by ethoxycarbonylnitrenium ion generated from ethyl azidoformate in the presence of trifluoroacetic acid Hiroshi Takeuchi and Eiji Mastubara pg 981; DOI: 10.1039/P19840000981 |
Afromontoside. A new cytotoxic principle from Dracaena afromontana K. Sambi Reddy Mohammed S. Shekhani David E. Berry David G. Lynn and Sidney M. Hecht pg 987; DOI: 10.1039/P19840000987 |
Triazines and related products. Part 26. Synthesis and chemistry of bicyclic analogues of the antitumour drug 2,4,6-tris(dimethylamino)-1,3,5-triazine (hexamethylmelamine) Simon P. Langdon Richard J. Simmonds and Malcolm F. G. Stevens pg 993; DOI: 10.1039/P19840000993 |
Triazines and related products. Part 27. Thermolysis of 4-anilino-1,2,3-benzotriazines Ghouse Uniasa Baig Malcolm F. G. Stevens and Keith Vaughan pg 999; DOI: 10.1039/P19840000999 |
Some reactions of alkoxythiocarbonyl derivatives with N,N-dimethylhydrazine Derek H. R. Barton Jean Boivin Soizic Legreneur and William B. Motherwell pg 1005; DOI: 10.1039/P19840001005 |
Oxymetallation. Part 18. Extensive rearrangement to a [4.2.1 ] skeleton in the bromodemercuriation of 2-bromomercurio-9-oxabicyclo[3.3.1]nonane A. J. Bloodworth and Henny J. Eggelte pg 1009; DOI: 10.1039/P19840001009 |
Biosynthesis of aspyrone, a metabolite of Aspergillus malleus. Incorporation studies with 14C- and 3H-labelled acetates and malonate R. Jeffrey Copeland Robert A. Hill David J. Hinchcliffe and James Staunton pg 1013; DOI: 10.1039/P19840001013 |
New polyketide metabolites from Aspergillus melleus: structural and stereochemical studies Mary J. Garson James Staunton and Peter G. Jones pg 1021; DOI: 10.1039/P19840001021 |
Biosynthesis of fungal metabolites: asperlactone and its relationship to other metabolites of Aspergillus melleus Richard G. Brereton Mary J. Garson and James Staunton pg 1027; DOI: 10.1039/P19840001027 |
Biomimetic syntheses of polyketide aromatics from pyrylium salts David A. Griffin Finian J. Leeper and James Staunton pg 1035; DOI: 10.1039/P19840001035 |
Reactions of the carbanion from an orsellinate derivative with electrophiles T. Adrian Carpenter Geoffrey E. Evans Finian J. Leeper James Staunton and Michael R. Wilkinson pg 1043; DOI: 10.1039/P19840001043 |
Biomimetic syntheses of polyketide aromatics from reaction of an orsellinate anion with pyrones and a pyrylium salt Finian J. Leeper and James Staunton pg 1053; DOI: 10.1039/P19840001053 |
The synthesis of ()-10a-homo-11a-carbathromboxane A1, a stable thromboxane A analogue Martin F. Ansell Jonathan S. Mason and Michael P. L. Caton pg 1061; DOI: 10.1039/P19840001061 |
Two syntheses of pinane thromboxane A2 Martin F. Ansell Michael P. L. Caton and Keith A. J. Stuttle pg 1069; DOI: 10.1039/P19840001069 |
Allenes. Part 42. Nucleophilic addition of hydroxylamine to allenic and acetylenic nitriles; synthesis of 3-alkyl-5-amino, 5-amino-3-phenyl-, and 3-amino-5-phenyl-isoxazoles Z. Tanee Fomum P. Forsche Asobo Stephen R. Landor and Phyllis D. Landor pg 1079; DOI: 10.1039/P19840001079 |
Total synthesis of ()-8-aza-9a,9b-dicarbaprostaglandin H1 Dominique Blondet and Christophe Morin pg 1085; DOI: 10.1039/P19840001085 |
Diastereospecific, enzymically catalysed transmethylation from S-methyl-L-methionine to L-homocysteine, a naturally occurring process Gunnar Grue-Sørensen Ebbe Kelstrup Anders Kjær and Jørgen Øgaard Madsen pg 1091; DOI: 10.1039/P19840001091 |
The stereochemistry of reduction of the 1- and 16-carbonyl group in the normal and 8,13-isogibberellins Zvitendo J. Duri James R. Hanson and Peter B. Hitchcock pg 1099; DOI: 10.1039/P19840001099 |
The partial synthesis of beyergibberellin A4 and A9 methyl esters Braulio M. Fraga Antonio G. Gonzalez Melchor G. Hernandez Zvitendo J. Duri and James R. Hanson pg 1105; DOI: 10.1039/P19840001105 |
The stereochemistry of tri-n-butyltin hydride reductions in the preparation of ring A desoxygibberellins Braulio M. Fraga Antonio G. Gonzalez Fernando G. Tellado Zvitendo J. Duri and James R. Hanson pg 1109; DOI: 10.1039/P19840001109 |
A convenient method for the synthesis of macrocyclic tetra-amides by double condensation reaction Yohmei Okuno Kiyoshi Horita Osamu Yonemitsu Kazue Shibata Toshiyuki Amemiya and Richard H. Holm pg 1115; DOI: 10.1039/P19840001115 |
The synthesis and metal binding characteristics of novel, isopolar phosphonate analogues of nucleotides G. Michael Blackburn David E. Kent and Friedrich Kolkmann pg 1119; DOI: 10.1039/P19840001119 |
Studies related to thietan-2-ones. Part 2. Conversion of a benzylpenicillin-derived thietan-2-one into D- and L-2-methylpenicillamines Martine M. L. Crilley and Richard J. Stoodley pg 1127; DOI: 10.1039/P19840001127 |
The acylation of 5H-2,3-benzodiazepines and 4H-thieno[2,3-d]- and 8H-thieno-[3,2-d]-[1,2]diazepines. Reactions with acid anhydrides and nucleophiles to give fused 7-substituted 1-acyl-1,2-diazepines David P. Munro and John T. Sharp pg 1133; DOI: 10.1039/P19840001133 |
Polyketide-derived fungal metabolites from Bipolaris sorokiniana and their significance in the biosynthesis of sterigmatocystin and aflatoxin B1 Catherine M. Maes and Pieter S. Steyn pg 1137; DOI: 10.1039/P19840001137 |
Corrigenda Josuke Tsunetsugu Masanobu Sugahara Kiyoshi Heima Yukio Ogawa Makoto Kosugi Masaru Sato Seiji Ebine Charles W. Shoppee and Reinhold J. Hart pg 1141; DOI: 10.1039/P19840001141 |
Electron deficient heteroaromatic ammonioamidates. Part 26. N-(quinazolin-3-io)amidates. Part 13. Phototransformations of an N-(quinazolin-3-io)thioamidate and of a 10bH-1,3,4-thiadiazolo[3,2-c]quinazoline, the ring isomer of an N-(quinazolin-3-io)thioamidate, and the photochemical formation of some 4,4-biquinazolinyls Magda Lempert-Sréter Károly Lempert and Jørgen Møller pg 1143; DOI: 10.1039/P19840001143 |
Peptidic thiacyclols. Synthesis and structural studies Giancarlo Zanotti Francesco Pinnen Gino Lucente Silvio Cerrini Walter Fedeli and Fernando Mazza pg 1153; DOI: 10.1039/P19840001153 |
Synthesis and 1H n.m.r. spectroscopic analysis of some 3,7-dioxabicyclo[3.3.0]octane lignans Vincent Vande Velde David Lavie Hugo E. Gottlieb Guido W. Perold and Feodor Scheinmann pg 1159; DOI: 10.1039/P19840001159 |
[2 + 2] Photocycloadditions of dichloromaleimide and dichloromaleic anhydride to cyclic olefins Yuan L. Chow and Yousry M. A. Naguib pg 1165; DOI: 10.1039/P19840001165 |
A versatile new synthesis of quinolines and related fused pyridines. Part 12. A general synthesis of 2-chloropyridines and 2-pyridones Otto Meth-Cohn and Keith T. Westwood pg 1173; DOI: 10.1039/P19840001173 |
Comparison between the epoxide ring-opening of 1-trimethylsilylcyclohexene oxide and some electrophilic additions to 1-trimethylsilylcyclohexene Giancarlo Berti Sergio Canedoli Paolo Crotti and Franco Macchia pg 1183; DOI: 10.1039/P19840001183 |
The behaviour of N-t-butyl-2,2-iminodiethanol towards some trivalent phosphorus compounds Fayez H. Osman Mahfouz M. Abdel Gawad and Mohamed M. Abbasi pg 1189; DOI: 10.1039/P19840001189 |
Synthesis of three series of diastereoisomeric bicyclic crown ethers and their stability constants with Group 1A cations David G. Parsons pg 1193; DOI: 10.1039/P19840001193 |
The deamination of 1-aminohexan-2-ol and 1-(aminomethyl)pentyl -D-galactopyranoside; a model study of the selective cleavage of the hydroxylysine-bound glycosyl residues of collagen Ping W. Tang and J. Michael Williams pg 1199; DOI: 10.1039/P19840001199 |
Synthesis of 3,6,17,20-tetrahydroxy-5-pregnan-11-one 6-hemisuccinate, a hapten for immunoassay of 3,17,20-trihydroxy-5-pregnan-11-one (pregnanetriolone) George Cooley and David N. Kirk pg 1205; DOI: 10.1039/P19840001205 |
Dibenzofuranones from 1 : 1 condensations between cyclohexanones and cyclohexane-1,3-diones John V. Greenhill Mohammad Ashraf Moten and Reiner Hanke pg 1213; DOI: 10.1039/P19840001213 |
New metabolic products of Verticillium lecanii. Part 2. 3,12,-Dihydroxy-4,4,14-trimethyl-5-pregna-7,9(11)-diene-20S-carboxylic acid and 4,4,14-trimethyl-3-oxo-5-pregna-7,9(11)-diene-20S-carboxylic acid John Frederick Grove pg 1219; DOI: 10.1039/P19840001219 |
n-Butyl-lithium-induced cleavage of several dithioacetals derived from diaryl ketones Hideyuki Ikehira Shigeo Tanimoto and Tatsuo Oida pg 1223; DOI: 10.1039/P19840001223 |
The chemistry of some 2-aminothiazol-4-ylacetic acid derivatives and the synthesis of derived penicillins Kenneth D. Hardy Frank P. Harrington and Andrew V. Stachulski pg 1227; DOI: 10.1039/P19840001227 |
A specific and efficient synthesis of ()-dihydrocorynantheol Bruno Danieli Giordano Lesma Giovanni Palmisano and Stefano Tollari pg 1237; DOI: 10.1039/P19840001237 |
Ketene. Part 21. Reactions of heterocumulenes with nitrones Andrew R. Evans Mushtaq Hafiz and Giles A. Taylor pg 1241; DOI: 10.1039/P19840001241 |
Structure of alcohols obtained by reaction of aldehydes and ketones with ortho-lithiated oxazolines Isabelle M. Dordor John M. Mellor and Peter D. Kennewell pg 1247; DOI: 10.1039/P19840001247 |
Reaction of oxazolines with phosphorus oxychloride Isabelle M. Dordor John M. Mellor and Peter D. Kennewell pg 1253; DOI: 10.1039/P19840001253 |
Substitution and elimination reactions of 3- and 4-alkyl-2H-1-benzopyrans with organoaluminium and organomagnesium reagents Angel Alberola Alfonso González Ortega Rafael Pedrosa José Luis Pérez Bragado and Martina Vicente pg 1259; DOI: 10.1039/P19840001259 |
The protection of thymine and guanine residues in oligodeoxyribonucleotide synthesis Colin B. Reese and Philip A. Skone pg 1263; DOI: 10.1039/P19840001263 |
A biomimetic synthesis of the novel 6,7-oxazine ring-fused dehydroaporphine alkaloid duguenaine George R. Lenz and Francis J. Koszyk pg 1273; DOI: 10.1039/P19840001273 |
Anthracyclinones. Part 2. The use of 1,2:5,6-di-O-isopropylidene--D-glucofuranose as a chiral template precursor in an anthracyclinone synthesis David J. Mincher and Gordon Shaw pg 1279; DOI: 10.1039/P19840001279 |
Synthesis and stereochemical analysis of 2-amino-1,2,3,4-tetrahydro-1,4-methanonaphthalene-2-carboxylic acid, a conformationally rigid phenylalanine derivative W. John Layton Stanford L. Smith Peter A. Crooks Trevor Deeks and Roger D. Waigh pg 1283; DOI: 10.1039/P19840001283 |
Facile regio- and stereo-specific allylic oxidation of gem-dimethyl olefins via addition of benzenesulphenyl chloride. Synthesis of allylic oxygenated terpenes Yukio Masaki Kinji Hashimoto Kazuhiko Sakuma and Kenji Kaji pg 1289; DOI: 10.1039/P19840001289 |
Photochemical syntheses of amino- and hydroxy-1,4-naphthoquinones with high selectivity Masaru Matsuoka Koichi Takagi Hideaki Tajima Kenji Ueda and Teijiro Kitao pg 1297; DOI: 10.1039/P19840001297 |
Synthesis of tropolone derivatives Masatoshi Yamato Kuniko Hashigaki Nobuhiko Kokubu and Yukari Nakato pg 1301; DOI: 10.1039/P19840001301 |
Synthetic studies on aromatic sesquiterpenoids: synthesis of curcumene ether by olefin cyclisation Tetsuji Kametani Kuniaki Kawamura Masayoshi Tsubuki and Toshio Honda pg 1305; DOI: 10.1039/P19840001305 |
Structure elucidation of sesbanimide using high-field n.m.r. spectroscopy Charles P. Gorst-Allman Pieter S. Steyn Robert Vleggaar and Nathaniël Grobbelaar pg 1311; DOI: 10.1039/P19840001311 |
A convenient procedure for the deoxygenation and homologation of D-ribose derivatives Stephen V. Attwood and Anthony G. M. Barrett pg 1315; DOI: 10.1039/P19840001315 |
Rearrangement of rosifoliol epoxides: transformation of eudesmane to valencane sesquiterpene types Robert Ramage and Ian A. Southwell pg 1323; DOI: 10.1039/P19840001323 |
Pyrrolizidine alkaloids. Biosynthesis of trichodesmic acid J. Alastair Devlin and David J. Robins pg 1329; DOI: 10.1039/P19840001329 |
Regioselective Claisen rearrangements in indoles Christopher J. Moody pg 1333; DOI: 10.1039/P19840001333 |
The acetylation of naphthoquinones. The synthesis of 3-acetyl-5-methoxy- and 3-acetyl-5,7-dimethoxy-1,4-naphthoquinones Trevor A. Chorn Robin G. F. Giles Ivan R. Green Victor I. Hugo Peter R. K. Mitchell and Selwyn C. Yorke pg 1339; DOI: 10.1039/P19840001339 |
Studies on the hydrolysis of clavulanic acid Malcolm J. Finn Michael A. Harris Eric Hunt and Iskander I. Zomaya pg 1345; DOI: 10.1039/P19840001345 |
Formation of a cyclopropane ester on a polymer support: effect of the macromolecular backbone on the stereoselectivity of cyclization Paulette Viout and Isabelle Artaud pg 1351; DOI: 10.1039/P19840001351 |
Phosphinamides: a new class of amino protecting groups in peptide synthesis Robert Ramage David Hopton Maxwell J. Parrott George W. Kenner and Geoffrey A. Moore pg 1357; DOI: 10.1039/P19840001357 |
Synthesis of spiroacetals using organoselenium-mediated cyclisation reactions. X-Ray molecular structure of (2S,8R)-8-methyl-2-phenyl-1,7-dioxaspiro[5.5]undecan-4(R)-ol Annette M. Doherty Steven V. Ley Barry Lygo and David J. Williams pg 1371; DOI: 10.1039/P19840001371 |
1,1-Dihalogenocyclopropanes derived from terpenes. The stereochemistry of cyclopropylidene insertion into carbon–hydrogen bonds adjacent to alcohols Mark S. Baird Sheila R. Buxton and Peter Sadler pg 1379; DOI: 10.1039/P19840001379 |
Photochemistry of chloroacetanilide derivatives: rearrangement, cyclization, and solvolysis Baldev Kumar Ravinder M. Mehta Subhash C. Kalra and Nirmal Kaur pg 1387; DOI: 10.1039/P19840001387 |
Reactions involving fluoride ion. Part 30. Preparation and reactions of epoxides derived from perfluoroalkyl substituted alkenes Martin R. Bryce Richard D. Chambers and Julian R. Kirk pg 1391; DOI: 10.1039/P19840001391 |
13C n.m.r. examination of ethyl cyano(arylhydrazono)acetates Durgeshwari Prasad Nagendra Prasad Radha M. Prasad Robert J. Ferrier and Stephen M. Milgate pg 1397; DOI: 10.1039/P19840001397 |
Dehydrogenation of indolines to indoles via azasulphonium salts or N-chloramines Masami Kawase Yuko Miyake and Yasuo Kikugawa pg 1401; DOI: 10.1039/P19840001401 |
Structure of a peptidal antibiotic P168 produced by Paecilomyces lilacinus(Thorn) Samson Akira Isogai Akinori Suzuki Saburo Tamura Shizuo Higashikawa and Shimpei Kuyama pg 1405; DOI: 10.1039/P19840001405 |
The synthesis of some novel deoxyhumulone analogues. Observations on the air-oxidation of 2,4,6-trihydroxy-3-isopentyl-5-(3-methylbut-2-enyl)isovalerophenone and its corresponding humulone derivatives Martin R. Cann Anne-Marie Davis and Patrick V. R. Shannon pg 1413; DOI: 10.1039/P19840001413 |
The reaction of 1-phenyl-4-vinylpyrazole with diethyl azodicarboxylate. X-Ray molecular structure of 1,2-bisethoxycarbonyl-1-[2-hydroxy-2-(1-phenylpyrazol-4-yl)ethyl]hydrazine R. Alan Jones Belen Abarca Gonzalez Jose Sepulveda Arques Juan Quilez Pardo and (the late) Trevor J. King pg 1423; DOI: 10.1039/P19840001423 |
The reaction of C-azidohydrazones with enamines Luca Bruché Luisa Garanti and Gaetano Zecchi pg 1427; DOI: 10.1039/P19840001427 |
The 2s+ 2s photocycloadditions of triplet pyrene to cyclohexa-1,3-diene Masaru Kimura Kastumi Nukada Kyosuke Satake Shiro Morosawa and Keiestu Tamagake pg 1431; DOI: 10.1039/P19840001431 |
A novel construction of the C ring of an aromatic steroid: new syntheses of equilenin and isoequilenin Nurani S. Narasimhan and Chintamani P. Bapat pg 1435; DOI: 10.1039/P19840001435 |
Isolation and structure determination of -pyrufuran, a third induced antifungal dibenzofuran from the wood of Pyrus communis L. infected with Chondrostereum purpureum(Pers. ex Fr.) Pouzar Malcolm S. Kemp and Raymond S. Burden pg 1441; DOI: 10.1039/P19840001441 |
Isolation and structure determination of cotonefuran, an induced antifungal dibenzofuran from Cotoneaster lactea W.W.Sm. Raymond S. Burden Malcolm S. Kemp Christopher W. Wiltshire and John D. Owen pg 1445; DOI: 10.1039/P19840001445 |
The reactivity of organophosphorus compounds. Part 36. Pyrolyses of 2-alkoxy-2,3-dihydro-1,3,2-benzoxazaphosph(V)oles J. I. G. Cadogan James B. Husband and Hamish McNab pg 1449; DOI: 10.1039/P19840001449 |
Revised structure of kribine Robert Verpoorte Wenche Rolfsen and Lars Bohlin pg 1455; DOI: 10.1039/P19840001455 |
Benzomorphan related compounds. Part 20. Synthesis of B-norbenzomorphans via 2-aryl-4-piperidones Joan Bosch Mario Rubiralta Montserrat Moral and Jordi Bolós pg 1459; DOI: 10.1039/P19840001459 |
Synthesis and properties of cyclohepta[de]naphthalene-7,8-dione, o-pleiadienequinone Josuke Tsunetsugu Mariko Kanda Makoto Takahashi Kazuo Yoshida Hiroshi Koyama Kazuo Shiraishi Yutaka Takano Masaru Sato and Seiji Ebine pg 1465; DOI: 10.1039/P19840001465 |
Synthesis, properties, and biological activity of some nucleoside cyclic phosphoramidates A. Stanley Jones Christopher McGuigan Richard T. Walker Jan Balzarini and Erik de Clercq pg 1471; DOI: 10.1039/P19840001471 |
Heterocyclic studies. Part 42. Pyrimido[5,4-d][1,2,3]triazines and some related tricyclic compounds Jim Clark and George Varvounis pg 1475; DOI: 10.1039/P19840001475 |
Synthesis of some new tetra-aryl porphyrins for studies in solar energy conversion. Part 2. Asymmetric porphyrins Lionel R. Milgrom pg 1483; DOI: 10.1039/P19840001483 |
Approaches to cytochalasan synthesis: preparation and Diels–Alder reactions of 3-alkyl- and 3-acyl-3-pyrrolin-2-ones Shaun A. Harkin Onkar Singh and Eric J. Thomas pg 1489; DOI: 10.1039/P19840001489 |
Preparation of some thiopyranopyridine derivatives Kenneth Clarke John Goulding and Richard M. Scrowston pg 1501; DOI: 10.1039/P19840001501 |
A new regiospecific synthesis of 1,4-dihydroxyxanthones Bruno Simoneau and Paul Brassard pg 1507; DOI: 10.1039/P19840001507 |
Dye-sensitized photo-oxygenation of chalcones H. Mohindra Chawla and Kakoli Chakrabarty pg 1511; DOI: 10.1039/P19840001511 |
Condensed cyclic and bridged-ring systems. Part 10. Alumina-induced regioselective intramolecular alkylations of cis- and trans-4a-(2-methylsulphonyloxyethyl)-3,4,4a,9,10,10a-hexahydrophenanthren-2(1H)-ones Gopa Bhattacharjee (née Sinha) Usha Ranjan Ghatak and Ajit K. Chakravarty pg 1515; DOI: 10.1039/P19840001515 |
Preparation of 3-methoxycarbonylpropyl -D- and 7-methoxycarbonylhexyl -D-galactopyranosides: spacer-arm glycosides for branched oligosaccharide synthesis Peter M. Collins and Hansjörg Eder pg 1525; DOI: 10.1039/P19840001525 |
Dioxolanones as synthetic intermediates. Part 1. Synthesis of -keto acids, -keto aldehydes, and -ketols Robert Ramage Gareth J. Griffiths Fiona E. Shutt and John N. A. Sweeney pg 1531; DOI: 10.1039/P19840001531 |
Dioxolanones as synthetic intermediates. Part 2. Synthesis of tetronic acids and pulvinones Robert Ramage Gareth J. Griffiths Fiona E. Shutt and John N. A. Sweeney pg 1539; DOI: 10.1039/P19840001539 |
Dioxolanones as synthetic intermediates. Part 3. Biomimetic synthesis of pulvinic acids Robert Ramage Gareth J. Griffiths and John N. A. Sweeney pg 1547; DOI: 10.1039/P19840001547 |
Dioxolanones as synthetic intermediates. Part 4. Biomimetic synthesis of multicolanic acid Robert Ramage and Patrick P. McCleery pg 1555; DOI: 10.1039/P19840001555 |
Carbon tetrachloride–dimethyl sulphone–potassium hydroxide–t-butyl alcohol: a convenient new reagent for gem-dichloromethylenation of alkenes Chi-Duen Poon Po-Wai Yuen Tim-On Man Chun-Sing Li and Tze-Lock Chan pg 1561; DOI: 10.1039/P19840001561 |
Thermolysis of polyazapentadienes. Part 6. Gas-phase cyclisation of 1,5-diaryl-1,5-diazapentadienes: mechanistic aspects and some synthetic applications Hamish McNab and M. Elizabeth-Ann Murray pg 1565; DOI: 10.1039/P19840001565 |
Thermolysis of polyazapentadienes. Part 7. An unambiguous route to 7-substituted quinolines from cinnamaldehyde derivatives Clare L. Hickson and Hamish McNab pg 1569; DOI: 10.1039/P19840001569 |
The characterization of two novel bufadienolides, lanceotoxins A and B from Kalanchoe lanceolata[Forssk.] Pers Lourens A. P. Anderson Pieter S. Steyn and Fanie R. van Heerden pg 1573; DOI: 10.1039/P19840001573 |
Pyrrolylpolyenes. Part 6. Synthesis of wallemia A and wallemia E Fawzi R. Ahmed and Trevor P. Toube pg 1577; DOI: 10.1039/P19840001577 |
Formation of di-iron hexacarbonyl complexes of 3H-1,2-diazepines and the effects of complexation on ring inversion and the rate of sigmatropic hydrogen migration Carl B. Argo and John T. Sharp pg 1581; DOI: 10.1039/P19840001581 |
Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5-yl)triazenes Richard N. Butler Declan P. Shelly and Victor C. Garvin pg 1589; DOI: 10.1039/P19840001589 |
Indoloquinolizidine alkaloids. A highly stereoselective synthesis of ()-deplancheine using a dienetricarbonyliron(0) complex Giordano Lesma Giovanni Palmisano and Stefano Tollari pg 1593; DOI: 10.1039/P19840001593 |
Nuclear modification of clavulanic acid. Preparation of optically active 1-oxaceph-3-ems Gerald Brooks Brian C. Gasson T. Trefor Howarth Eric Hunt and Kong Luk pg 1599; DOI: 10.1039/P19840001599 |
Naturally occurring dibenzofurans. Part 4. Synthesis of dibenzofurandiols by annelation of benzofurans Christopher F. Carvalho and Melvyn V. Sargent pg 1605; DOI: 10.1039/P19840001605 |
Naturally occurring dibenzofurans. Part 5. Synthesis of melacarpic acid Christopher F. Carvalho and Melvyn V. Sargent pg 1613; DOI: 10.1039/P19840001613 |
Naturally occurring dibenzofurans. Part 6. Synthesis of didymic acid Christopher F. Carvalho and Melvyn V. Sargent pg 1621; DOI: 10.1039/P19840001621 |
Direct formation of 5-phospholes from trialkyl phosphites and dimethyl acetylenedicarboxylate. Alkoxyphosphonium ylides as reactive intermediates and stable products Julian C. Caesar D. Vaughan Griffiths John C. Tebby and Stuart E. Willetts pg 1627; DOI: 10.1039/P19840001627 |
c-Thioacylation by the Willgerodt–Kindler reaction. Structure of the anomalous products from salicylaldehydes. X-Ray crystal structure of the betaine from 1,2-dimethyl-1,4,5,6-tetrahydropyrimidine, sulphur, and 3,5-dichlorosalicylaldehyde Srinivasachari Rajappa Bhagwan G. Advani and Gopinath Kartha pg 1631; DOI: 10.1039/P19840001631 |
The structures of four diarylheptanoid glycosides from the female flowers of Alnus serrulatoides Shinji Ohta Tadashi Aoki Toshifumi Hirata and Takayuki Suga pg 1635; DOI: 10.1039/P19840001635 |
Palladium-catalysed synthesis of endo- and exo-brevicomin and related di- and tri-oxabicyclo[x.2.1] systems Norman T. Byrom Ronald Grigg Boonsong Kongkathip Gerald Reimer and Alan R. Wade pg 1643; DOI: 10.1039/P19840001643 |
Synthesis and C.d. spectra of 6,6a,7,11b-tetrahydro-5H-indeno[2,1-c]-isoquinoline derivatives Sanji Hagishita Motoo Shiro and Kaoru Kuriyama pg 1655; DOI: 10.1039/P19840001655 |
Replacement of primary amino groups by hydrogen via tetrahydrodibenzacridinium salts Alan R. Katritzky Susana Bravo-Borja Azzahra M. El-Mowafy and Maria L. Lopez-Rodriguez pg 1671; DOI: 10.1039/P19840001671 |
Photobromination of carbohydrate derivatives. Part 7. Reaction of furanose derivatives with bromine: 4-bromo- and 4-fluoro-aldofuranose and -nucleoside esters Robert J. Ferrier and Stephen R. Haines pg 1675; DOI: 10.1039/P19840001675 |
Photobromination of carbohydrate derivatives. Part 8. Reaction of furanose derivatives with N-bromosuccinimide. X-Ray molecular structure of 1-O-acetyl-2,5,6-tri-O-benzoyl-4-hydroxy-3,4-O-(-succinimidobenzylidene)--D-galactofuranose Robert J. Farrier Stephen R. Haines Graeme J. Gainsford and Eric J. Gabe pg 1683; DOI: 10.1039/P19840001683 |
Unsaturated carbohydrates. Part 26. Alkenes from 4-bromohexofuranose esters; reactions of 5-deoxyald-4-enofuranose derivatives in the presence of mercury(II) ions Robert J. Farrier and Stephen R. Haines pg 1689; DOI: 10.1039/P19840001689 |
A cyclopropanol derivative as an intermediate for the preparation of A-homopimarane Paolo Ceccherelli Massimo Curini Rita Coccia and Marco Diamantini pg 1693; DOI: 10.1039/P19840001693 |
Study of a model system for asymmetric induction in [2C + 2C] photoannelation reactions Kathleen Bruneel Denis De Keukeleire and Maurits Vandewalle pg 1697; DOI: 10.1039/P19840001697 |
A new rearrangement product of thebaine, isolated from Papaver bracteatum Lindl. Structural assignment of thebaine N-oxides Hubert G. Theuns Richard H. A. M. Janssen Hubertus W. A. Biessels Francesco Menichini and Cornelis A. Salemink pg 1701; DOI: 10.1039/P19840001701 |
The formation of complexes between aza derivatives of crown ethers and primary alkylammonium salts. Part 7. Chiral derivatives of aza crown ethers Derek J. Chadwick Ian A. Cliffe Ian O. Sutherland and Roger F. Newton pg 1707; DOI: 10.1039/P19840001707 |
Pyrimidine derivatives and related compounds. Part 50. Photochemical reaction of 5-substituted 6-azido-1,3-dimethyluracils with nucleophiles. Ring transformation of pyrimidine to 1,3,5-triazepine and hydantoin ring systems Kosaku Hirota Kazuo Maruhashi Norihiko Kitamura Tetsuji Asao and Shigeo Senda pg 1719; DOI: 10.1039/P19840001719 |
Reaction of 3-phenylglycidic esters. Part 1. Stereoselective opening of the oxirane ring of trans-3-phenylglycidic esters with 2-nitrothiophenols and the effect of various catalysts thereon Tomiki Hashiyama Hirozumi Inoue Mikihiko Konda and Mikio Takeda pg 1725; DOI: 10.1039/P19840001725 |
The synthesis of the epoxide and some other possible metabolites of precocene I Richard C. Jennings and Anthony P. Ottridge pg 1733; DOI: 10.1039/P19840001733 |
Rearrangement and participation reactions occurring during the bromination of 7-trimethylsilylnitronorbornenes. Evidence for a discrete carbocation to silicon Joseph P. Michael Norman F. Blom and Jan C. A. Boeyens pg 1739; DOI: 10.1039/P19840001739 |
Palladium- and rhodium-catalysed cyclisation of 1,6-, 1,7- and 1,8-dienes to cyclopentenes and methylenecyclopentenes. Crystal structure of dichloro(4,4-diacetylhepta-1,6-diene)platinum(II) Ronald Grigg John F. Malone Thomas R. B. Mitchell Ashok Ramasubbu and Ronald M. Scott pg 1745; DOI: 10.1039/P19840001745 |
The structure of wightianone, the pigment of a clathrate from Calophyllum wightianum Francis M. Dean Hafizzullah Khan Najme Minhaj Satya Prakash and Asif Zaman pg 1755; DOI: 10.1039/P19840001755 |
Novel rearrangement of the ionophore antibiotic X-14547A (indanomycin) and related derivatives induced by lithium tetrafluoroborate Martin P. Edwards and Steven V. Ley pg 1761; DOI: 10.1039/P19840001761 |
Studies on a synthesis of (RS)-mevalonic acid lactone Esfandiar Bardshiri Thomas J. Simpson A. Ian Scott and Kozo Shishido pg 1765; DOI: 10.1039/P19840001765 |
Baeyer–Villiger-type oxidation of an immonium group: the structural establishment of naturally occurring amides related to benzo[c]phenanthridine alkaloids Hisashi Ishii Tsutomu Ishikawa Sheng-Teh Lu and Ih-Sheng Chen pg 1769; DOI: 10.1039/P19840001769 |
Further investigations of the stereochemistry of electrophilic addition reactions of the steroidal C-22 double bond Yutaka Hirano Suguru Takatsuto and Nobuo Ikekawa pg 1775; DOI: 10.1039/P19840001775 |
Synthesis and thermal racemization of the 3,4-oxide metabolite of benzo[c] phenanthrene Suresh K. Balani Derek R. Boyd Ruth M. E. Greene and Donald M. Jerina pg 1781; DOI: 10.1039/P19840001781 |
Two new protected acyl protecting groups for alcoholic hydroxy functions Jonathan M. Brown Chris Christodoulou Colin B. Reese and Giovanni Sindona pg 1785; DOI: 10.1039/P19840001785 |
Reactions of perfluoronitroxides with sulphur dioxide Ahmad Arfaei and Sydney Smith pg 1791; DOI: 10.1039/P19840001791 |
Nitrogen bridgehead compounds. Part 41. Ring transformation of nitrogen bridgehead ring systems István Hermecz Zoltán Mészáros Kálmán Simon László Szabó and Zoltán Pál pg 1795; DOI: 10.1039/P19840001795 |
Nitrogen bridgehead compounds. Part 42. Cyclization of diethyl 2-(2-pyridyl-aminomethylene)-succinates and -glutarates in ethanolic sodium ethoxide Lelle Vasvári-Debreczy István Hermecz and Zoltán Mészáros pg 1799; DOI: 10.1039/P19840001799 |
Observations on various silyl-cuprate reagents Ian Fleming and Trevor W. Newton pg 1805; DOI: 10.1039/P19840001805 |
A synthesis of allylsilanes in which the silyl group is at the more-substituted end of the allyl group Ian Fleming and David Waterson pg 1809; DOI: 10.1039/P19840001809 |
Controlling the outcome of a carbocation-initiated cyclisation Hak-Fun Chow and Ian Fleming pg 1815; DOI: 10.1039/P19840001815 |
18-Substituted steroids. Part 11. Synthesis of 3,16,18-trihydroxyandrost-5-en-17-one, a neonatal urinary metabolite, and the 3,16,18-triacetate of its 16-epimer Rabeya Das and David N. Kirk pg 1821; DOI: 10.1039/P19840001821 |
Sulphoxide substituted pyridines as phase-transfer catalysts for nucleophilic displacements and alkylations Naomichi Furukawa Satoshi Ogawa Tsutomu Kawai and Shigeru Oae pg 1833; DOI: 10.1039/P19840001833 |
ipso-Substitution of a sulphinyl or sulphonyl group attached to pyridine rings and its application for the synthesis of macrocycles Naomichi Furukawa Satoshi Ogawa Tsutomu Kawai and Shigeru Oae pg 1839; DOI: 10.1039/P19840001839 |
The use of 3-acetoxy-1-trimethylsilylbutadiene in the synthesis of anthracyclinone derivatives Philip C. Bulman-Page and Steven V. Ley pg 1847; DOI: 10.1039/P19840001847 |
Pyrimidine derivatives and related compounds. Part 48. Uracil ring transformation: conversion of 5-nitrouracils into 5-carbamoyluracils Kosaku Hirota Yukio Kitade and Shigeo Senda pg 1859; DOI: 10.1039/P19840001859 |
Bridgehead substitution reactions of 3-methoxy-4-azahomoadamantane via N-acyliminium ions. A novel route to some [3,4]-fused 4-azahomoadamantane heterocycles Tadashi Sasaki Shoji Eguchi Takashi Okano and Norihiro Nakamura pg 1863; DOI: 10.1039/P19840001863 |
Thermal cycloaddition reactions of thiocarbonyl compounds. Part 1. A novel [4 + 2] cycloaddition reaction of adamantanethione with ,-unsaturated carbonyl compounds Tomonori Katada Shoji Eguchi Toshiyuki Esaki and Tadashi Sasaki pg 1869; DOI: 10.1039/P19840001869 |
Starfish saponins. Part 14. Structures of the steroidal glycoside sulphates from the starfish Marthasterias glacialis Ines Bruno Luigi Minale Cosimo Pizza Franco Zollo Raffaele Riccio and Francis M. Mellon pg 1875; DOI: 10.1039/P19840001875 |
Stereoselective thioglycoside syntheses. Part 6. Aryl 4-thiomalto-oligosaccharides as chromogenic substrates for kinetic studies with -amylase Michèle Blanc-Muesser Jacques Defaye Hugues Driguez Guy Marchis-Mouren and Christiana Seigner pg 1885; DOI: 10.1039/P19840001885 |
Fused mesoionic heterocycles: synthesis of 1,3,4-triazolo[3,2-a]pyridine derivatives Pedro Molina Mateo Alajarin Antonio Arques Raimundo Benzal and Higinio Hernandez pg 1891; DOI: 10.1039/P19840001891 |
Synthesis of 4H-1,4-benzothiazines via lithiation alpha to sulphur of 2-acylaminophenyl alkyl sulphides, sulphoxides, and sulphones Francesco Babudri Saverio Florio Anna Maria Vitrani and Leonardo Di Nunno pg 1899; DOI: 10.1039/P19840001899 |
Intramolecular reactions of N-nitrenes with alkenes Robert S. Atkinson John R. Malpass Karen L. Skinner and Katherine L. Woodthorpe pg 1905; DOI: 10.1039/P19840001905 |
Phenanthrene synthesis: the synthesis of juncunone and the micandrols-A, B, E, and F Christopher F. Carvalho and Melvyn V. Sargent pg 1913; DOI: 10.1039/P19840001913 |
Phenanthrene synthesis: coeloginin a novel 9,10-dihydrophenanthrene from the orchid Coelogyne cristata Melvyn V. Sargent and Edi Stanojevic pg 1919; DOI: 10.1039/P19840001919 |
3-Oxidopyrylium adducts from the pyrolysis of cellulose Richard H. Furneaux Jennifer M. Mason and Ian J. Miller pg 1923; DOI: 10.1039/P19840001923 |
Synthesis and reactions of N-indol-3-ylmethylalkylammes and related compounds El-Sayed M. Afsah and Anthony H. Jackson pg 1929; DOI: 10.1039/P19840001929 |
Synthesis of imidazoles from alkenes Michael Casey Christopher J. Moody and Charles W. Rees pg 1933; DOI: 10.1039/P19840001933 |
Cyclic organophosphorus compounds. Part 20. Structural correlations in the 2-amino-4-methyl-1,3,2-dioxaphosphinane series. X-Ray molecular structure of cis-2-t-butylamino-4-methyl-1,3,2-dioxaphosphinane 2-oxide Ronald S. Edmundson and (the late) Trevor J. King pg 1943; DOI: 10.1039/P19840001943 |
Lithiation to heteroatoms: eliminative ring fission of heterocycles Francesco Babudri Saverio Florio Antonia Reho and Giuseppe Trapani pg 1949; DOI: 10.1039/P19840001949 |
Naphthoquinone mono- and di-methide lactones John L. Carey Charles A. Shand Ronald H. Thomson and Colin W. Greenhalgh pg 1957; DOI: 10.1039/P19840001957 |
Dimeric and trimeric flavonoids containing a cyclopentane ring: 6,7-diaryl-6a,7,13,13a-tetrahydro-6H-7,13-methano[1]benzopyrano[3,4-c][1]benzoxepins Ben R. Brown and A. William R. Tyrrell pg 1963; DOI: 10.1039/P19840001963 |
Oxidation of phenols by molecular oxygen catalysed by transition metal complexes. Comparison between the activity of various cobalt and manganese complexes and the role of peroxy intermediates Maryvonne Frostin-Rio Danièle Pujol Claude Bied-Charreton Martine Perrée-Fauvet and Alain Gaudemer pg 1971; DOI: 10.1039/P19840001971 |
De novo synthesis of carbohydrates. Part 14. Preparation of 4-aminolyxose derivatives. X-Ray molecular structure of ethyl 6-ethoxycarbonylamino-8-hydroxymethyl-3,3-dimethyl-2,4-dioxa-7-azabicyclo[3.3.0]octane-7-carboxylate Andrew K. Forrest Richard R. Schmidt Gottfried Huttner and Ibrahim Jibril pg 1981; DOI: 10.1039/P19840001981 |
Synthesis of monoamides of methotrexate from L-glutamic acid monoamide t-butyl esters David J. Antonjuk Deborah K. Boadle H. T. Andrew Cheung and Trung Q. Tran pg 1989; DOI: 10.1039/P19840001989 |
Heterocyclic studies. Part 43. Thieno[2,3-d:4,5-d]dipyrimidines Jim Clark and George Hitiris pg 2005; DOI: 10.1039/P19840002005 |
Ring transformation and reactions of 2-amino-4,5-dihydrofuran-3,4-dicarbonitriles Vicente J. Arán Miguel A. Pérez and José L. Soto pg 2009; DOI: 10.1039/P19840002009 |
Synthesis and chiroptical properties of bridged 2,2-diaminobiphenyl derivatives Kaoru Seno Sanji Hagishita Tomohiro Sato and Kaoru Kuriyama pg 2013; DOI: 10.1039/P19840002013 |
Non-template syntheses and monoalkylation of an aza macrocycle containing 2,2-bipyridine Shojiro Ogawa Noriyuki Kishii and Shinsaku Shiraishi pg 2023; DOI: 10.1039/P19840002023 |
The acylation of 5H-2,3-benzodiazepines. Reactions of 4-phenyl-5H-2,3-benzodiazepine with acyl chlorides to give N-acylaminoisoquinolines and/or acylated dimers. X-Ray molecular structure of 5,14-diacetyl-4,5,8,9-tetrahydro-2,7-diphenyl-4,8-o-benzeno-3,9-imino-3H-3,5,6-benzotriazacycloundecine Keith R. Motion David P. Munro John T. Sharp and Malcolm D. Walkinshaw pg 2027; DOI: 10.1039/P19840002027 |
Photocyclisation of enamides. Part 21. Synthesis of benzo[a]quinolizines related to the alkaloids emetine and flavopereirine Ichiya Ninomiya Yukiko Tada Toshiko Kiguchi Okiko Yamamoto and Takeaki Naito pg 2035; DOI: 10.1039/P19840002035 |
Synthesis of (24R)- and (24S)-24,28-epoxyergost-5-en-3-ols. Substrate stereospecificity in their metabolism in the insect Tenebrio molitor Francesco Nicotra Fiamma Ronchetti Giovanni Russo and Lucio Toma pg 2039; DOI: 10.1039/P19840002039 |
Stereochemical studies. Part 78. Saturated heterocycles. Part 65. Synthesis and spectroscopic studies of cis-5,6-trimethylene-, and cis- and trans-5,6-tetra-and -pentamethylene-1,3-oxazinan-4-ones Ferenc Fülöp Gábor Bernáth Pál Sohár and István Pelczer pg 2043; DOI: 10.1039/P19840002043 |
Conjugate additions to ,-unsaturated sulphoxides: syntheses of cyclopentenones and 9-deoxyprostanoids Peter J. Brown D. Neville Jones M. Akram Khan Nicholas A. Meanwell and Pamela J. Richards pg 2049; DOI: 10.1039/P19840002049 |
The synthesis of 8,10,12-triazaprostaglandin analogues: 1,2,4-triazolidine-3,5-dione derivatives David R. Adams Alan F. Barnes Frederick Cassidy and Mervyn Thompson pg 2061; DOI: 10.1039/P19840002061 |
Dearomatisation of 2-naphthol by oxidative nucleophilic substitution and oxidative electrophilic substitution Humberto Arzeno Derek H. R. Barton Reine-Marie Bergé-Lurion Xavier Lusinchi and B. Mario Pinto pg 2069; DOI: 10.1039/P19840002069 |
Dearomatisation of 2-naphthol by oxidative nucleophilic substitution: an efficient two-step process Derek H. R. Barton Reine-Marie Bergé-Lurion Xavier Lusinchi and B. Mario Pinto pg 2077; DOI: 10.1039/P19840002077 |
The synthesis of lignans and related structures using quinodimethanes and isobenzofurans: approaches to the podophyllins John Mann Susan E. Piper and Lilan K. P. Yeung pg 2081; DOI: 10.1039/P19840002081 |
Studies related to cyclopentanoid natural products. Part 3. Synthesis of pentenomycin and its racemate Michael Hetmanski Neil Purcell Richard J. Stoodley and Malcolm N. Palfreyman pg 2089; DOI: 10.1039/P19840002089 |
Synthesis of 5-iminopyrrol-2-one derivatives from 1,3-oxazines. Ring transformations via attack on the 2- or 6-position of 1,3-oxazines Motoi Yogo Kosaku Hirota and Yoshifumi Maki pg 2097; DOI: 10.1039/P19840002097 |
Metal-carbonyl-induced reaction of 2-isoxazolines. Ring cleavage and reduction by pentacarbonyliron or nonacarbonyldi-iron Makoto Nitta and Tomoshige Kobayashi pg 2103; DOI: 10.1039/P19840002103 |
Stereoisomerization in heterocyclic hydrazones derived from 2-acylpyridines and their oxidative cyclization with mercury(II) acetate and lead tetra-acetate to fused 1,2,4-triazoles and 1,2,3-triazolium systems Richard N. Butler and Seán M. Johnston pg 2109; DOI: 10.1039/P19840002109 |
Spirocyclic side-chain derivatives of penicillin and cephalosporin Peter G. Sammes Steven Smith and Barry C. Ross pg 2117; DOI: 10.1039/P19840002117 |
A synthetic route to dehydrosecodine analogues Paul D. Leeson pg 2125; DOI: 10.1039/P19840002125 |
The formation of enaminoenaminones from N-alkylaminomethylene derivatives of Meldrum's acid Helen J. Gordon Jane C. Martin and Hamish McNab pg 2129; DOI: 10.1039/P19840002129 |
Structure and biosynthesis of phomenoic acid, an antifungal compound isolated from Phoma lingam Tode Michel Devys Jean-Pierre Férézou Ravindra Satish Topgi Michel Barbier Jean-François Bousquet and Albert Kollmann pg 2133; DOI: 10.1039/P19840002133 |
A new synthetic approach to bruceantin via an intramolecular Diels–Alder reaction: stereoselective construction of the pentacyclic model system Kozo Shishido Tadamasa Saitoh Keiichiro Fukumoto and Tetsuji Kametani pg 2139; DOI: 10.1039/P19840002139 |
Carotenoids and related compounds. Part 38. Synthesis of (3RS,3RS)-alloxanthin and other acetylenes Anthony J. Davies Anakshi Khare Alan K. Mallams Ralph A. Massy-Westropp Gerard P. Moss and Basil C. L. Weedon pg 2147; DOI: 10.1039/P19840002147 |
Formal total synthesis of ()-pseudomonic acids from dihydropyran Richard F. W. Jackson Ralph A. Raphael John H. A. Stibbard and Raymond C. Tidbury pg 2159; DOI: 10.1039/P19840002159 |
Metacyclophane and related compounds. Part 11. Reaction of 8,16-bis(bromomethyl)[2.2]metacyclophane and 8,16-bis(bromomethyl)-5,13-di-t-butyl[2.2]metacyclophane with Grignard reagents Masashi Tashiro and Takehiko Yamato pg 2165; DOI: 10.1039/P19840002165 |
The conversion of gibberellic acid into steroid analogues James R. Hanson and Ling Yang-zhi pg 2173; DOI: 10.1039/P19840002173 |
Synthesis and physical properties of azapolycyclic hydrocarbons. Part 1. Preparation of 1-azabenzanthrone and its condensation products and their structural determination Satoshi Iwashima Toyotoshi Ueda Hitoshi Honda Toshitsugu Tsujioka Mitsuru Ohno Junji Aoki and Teruo Kan pg 2177; DOI: 10.1039/P19840002177 |
Formation of indoles, isoquinolines, and other fused pyridines from azidoacrylates Lothar Henn Deirdre M. B. Hickey Christopher J. Moody and Charles W. Rees pg 2189; DOI: 10.1039/P19840002189 |
Corrigenda Hiroshi Ishii Kazuo Tori Takehiko Tozyo Yohko Yoshimura Augusto C. Veronese Paolo Scrimin Giorgio Vecchiati Stella Sferra Ferruccio D'Angeli Kim Clausen Michael Thorsen Sven-Olov Lawesson David P. Munro and John T. Sharp pg 2197; DOI: 10.1039/P19840002197 |
Synthesis, characterisation, and transformations of a lipid cyclic peroxide Emanuele Bascetta Frank D. Gunstone and Charles M. Scrimgeour pg 2199; DOI: 10.1039/P19840002199 |
Synthesis of cyclic peroxides from methyl oleate Emanuele Bascetta and Frank D. Gunstone pg 2207; DOI: 10.1039/P19840002207 |
Attempted synthesis of (9Z)-methyl 12-hydroperoxyoctadec-9-enoate Emanuele Bascetta and Frank D. Gunstone pg 2217; DOI: 10.1039/P19840002217 |
Synthetic routes to thiazolo[3,2-a]pyrimidin-7-ones via 1-allyl-2-thiouracil Vinko kari Djurdja kari and Ankica imek pg 2221; DOI: 10.1039/P19840002221 |
The addition–elimination mechanism in the nucleophilic heteroaromatic substitution of 3-(4,4-dimethyl-4,5-dihydro-oxazol-2-yl)pyridine. Solvent effect on the regiochemistry of the addition reaction Albert E. Hauck and C. S. Giam pg 2227; DOI: 10.1039/P19840002227 |
Stereochemistry of olefin and fatty acid oxidation. Part 3. The allylic hydroperoxides from the autoxidation of methyl oleate Edwin N. Frankel Robert F. Garwood Bhupinder P. S. Khambay Gerard P. Moss and Basil C. L. Weedon pg 2233; DOI: 10.1039/P19840002233 |
Constitution of Hofmann's dimethylconiine and conylene Wesley Cocker Niall W. A. Geraghty and Patrick V. R. Shannon pg 2241; DOI: 10.1039/P19840002241 |
An investigation of the thermal decomposition of the methohydroxides and methodeuterio-oxides of some 5-N,N-dimethylaminopent-1-enes Wesley Cocker Niall W. A. Geraghty T. Brian H. McMurry and Patrick V. R. Shannon pg 2245; DOI: 10.1039/P19840002245 |
N-alkoxy-N-acylnitrenium ions as possible intermediates in intramolecular aromatic substitution: novel formation of N-acyl-3,4-dihydro-1H-2,1-benzoxazines and N-acyl-4,5-dihydro-1H,3H-2.1-benzoxazepine Stephen A. Glover André Goosen Cedric W. McCleland and Johan L. Schoonraad pg 2255; DOI: 10.1039/P19840002255 |
Regiospecific conversion of oxiranes, oxetanes, and lactones into difunctional nitrogen compounds via aminosilanes and aminostannanes Annamaria Papini Alfredo Ricci Maurizio Taddei Giancarlo Seconi and Pasquale Dembech pg 2261; DOI: 10.1039/P19840002261 |
Assignment of the 1H n.m.r. spectrum of heptamethyl dicyanocobyrinate in chloroform solution by two-dimensional 13C/1H chemical shift correlation spectroscopy Ludger Ernst pg 2267; DOI: 10.1039/P19840002267 |
Stereochemistry of the decarboxylation of -acetolactate (2-hydroxy-2-methyl-3-oxobutanoate) by the acetolactate decarboxylase of Klebsiella aerogenes David H. G. Crout Jennifer Littlechild Michael B. Mitchell and Stephen M. Morrey pg 2271; DOI: 10.1039/P19840002271 |
Steroids from the starfish Euretaster insignis: a novel group of sulphated 3,21-dihydroxysteroids Maria V. D'Auria Ester Finamore Luigi Minale Cosimo Pizza Raffaele Riccio Franco Zollo Michelle Pusset and Philippe Tirard pg 2277; DOI: 10.1039/P19840002277 |
Conversion of the naturally occurring amide alkaloids into O5 benzo[c]phenanthridinium alkaloids. A new synthetic sequence to antitumour benzo[c]phenanthridine alkaloids Hisashi Ishii Tsutomu Ishikawa Toshiko Watanabe Yuh-Ichiro Ichikawa and Eri Kawanabe pg 2283; DOI: 10.1039/P19840002283 |
Chemistry of bacterial endotoxins. Part 2. A practical synthesis of 6-O-{4-O-ammonio(hydrogen)phosphono-2-deoxy-2-[(3R)-3-hydroxytetradecanamido]--D-glucopyranosyl}-2-deoxy-2-[(3R)-3-hydroxytetradecanamido]-D-glucose Daniel Charon Michelle Mondange and Ladislas Szabó pg 2291; DOI: 10.1039/P19840002291 |
The synthesis and photochemical behaviour of some annelated tropones Martin G. Hicks Gurnos Jones and Hamid Sheikh pg 2297; DOI: 10.1039/P19840002297 |
Synthesis ofN,N-diacylindigotins (N,N-diacyl-2,2-bi-indolinylidene-3,3-diones)via an oxidative oxygen-to-nitrogen acyl shift of O,O-diacyl-leucoindigos(3,3-diacyloxy-2,2-bi-indolyls) Jun-ichiro Setsune Hirofumi Wakemoto Taizo Matsueda Toshikazu Matsuura Hideaki Tajima Teijiro Kitao Shoichi Ishihara and Ryoichi Yamamoto pg 2305; DOI: 10.1039/P19840002305 |
The structure of cyanoginosin-LA, a cyclic heptapeptide toxin from the cyanobacterium Microcystis aeruginosa Dawie P. Botes Albert A. Tuinman Philippus L. Wessels Cornelis C. Viljoen Heléne Kruger Dudley H. Williams Sitthivet Santikarn Richard J. Smith and Stephen J. Hammond pg 2311; DOI: 10.1039/P19840002311 |
Steroids. Part 21. Photorearrangement of steroidal nitronate salts and a N-butyl spiro-oxaziridine Graham J. Edge Syed H. Imam and Brian A. Marples pg 2319; DOI: 10.1039/P19840002319 |
Radical–nucleophilic substitution (SRN1) reactions. Part 2. Preparation and reactions of -nitrosulphides W. Russell Bowman Devajvoti Rakshit and Michael D. Valmas pg 2327; DOI: 10.1039/P19840002327 |
Total synthesis of PGD, methyl ester and 9-epi-PGD, methyl ester Andrew G. Cameron Alan T. Hewson and Alan H. Wadsworth pg 2337; DOI: 10.1039/P19840002337 |
Reaction of 3-hydroxycholesta-4,6-dienes with m-chloroperbenzoic acid Erwin Glotter and Michael Zviely pg 2345; DOI: 10.1039/P19840002345 |
Photolysis of diphenyl- and t-butyl(phenyl)-phosphinic azides: dimethyl sulphide as a nitrene trap, and its influence on the Curtius-like rearrangement Martin J. P. Harger and Sally Westlake pg 2351; DOI: 10.1039/P19840002351 |
Nitroacetamidation of styrenes A. Jon Bloom Martin Fleischmann and John M. Mellor pg 2357; DOI: 10.1039/P19840002357 |
Carbon-13 nuclear magnetic resonance spectra of eighteen derivatives of ent-kaur-16-en-19-oic acid Michael Hutchison Paul Lewer and Jake MacMillan pg 2363; DOI: 10.1039/P19840002363 |
C-nucleoside studies. Part 17. The synthesis of 3(5)-carbamoyl-5(3)--D ribofuranosylpyrazole (4-deoxypyrazofurin) and 4-amino-3(5)-carbamoyl-5(3)--D-ribofuranosylpyrazole J. Grant Buchanan Naveen K. Saxena and Richard H. Wightman pg 2367; DOI: 10.1039/P19840002367 |
Regioselective reductive ring-opening of 4-methoxybenzylidene acetals of hexopyranosides. Access to a novel protecting-group strategy. Part 1 Rolf Johansson and Bertil Samuelsson pg 2371; DOI: 10.1039/P19840002371 |
Oxidation of bis(2-hydroxy-1-naphthyl)methane and similar bisnaphthols with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone. Structure and synthesis of novel products Tirumalai R. Kasturi Betageri Rajasekhar Gonibella J. Raju Gowravaram Madhusudhan Reddy Ramamoorthy Sivaramakrishnan Narayanan Ramasubbu and Kailasam Venkatesan pg 2375; DOI: 10.1039/P19840002375 |
Naphtho[2,3-c]pyran-5,10-quinones. Syntheses of the racemates of quinone A, quinone A, and deoxyquinone A dimethyl ethers of 7-methoxyeleutherin, and of isoeleutherin Robin G. F. Giles Ivan R. Green Victor I. Hugo Peter R. K. Mitchell and Selwyn C. Yorke pg 2383; DOI: 10.1039/P19840002383 |
An investigation into the formation of benzo- and naphtho-pyrans by cyclisation of ortho-alkenyl(hydroxyalkyl)benzenes using either cerium(IV) ammonium nitrate or potassium t-butoxide in dimethylformamide Robin G. F. Giles Ivan R. Green and J. Alexandre X. Pestana pg 2389; DOI: 10.1039/P19840002389 |
The photocycloaddition of an 5-androst-1-en-3-one to olefins George R. Lenz pg 2397; DOI: 10.1039/P19840002397 |
Synthesis of ()-cis-6-methyltetrahydropyran-2-ylacetic acid, a natural product from Viverra civetta, using organoselenium-mediated cyclisation reactions Steven V. Ley Barry Lygo and Huguette Molines pg 2403; DOI: 10.1039/P19840002403 |
Acyl rearrangements in acylbenzoquinone cycloadducts Simon C. Cooper and Peter G. Sammes pg 2407; DOI: 10.1039/P19840002407 |
Preparation of azetidines from 1,3-aminopropanols Peter G. Sammes and Steven Smith pg 2415; DOI: 10.1039/P19840002415 |
Conversion of formycin into the fluorescent isoguanosine analogue 7-amino-3-(-D-ribofuranosyl)-1H-pyrazolo[4,3-d]pyrimidin-5(4H)-one Samarendra N. Bose Shiv Kumar R. Jeremy H. Davies Satinder K. Sethi and James A. McCloskey pg 2421; DOI: 10.1039/P19840002421 |
Polyhalogenoaromatic compounds. Part 52. Reactions of octachloronaphthalene with nucleophilic reagents and synthesis of some heptachloronaphthyl derivatives John H. Brady Nazir Tahir and Basil J. Wakefield pg 2425; DOI: 10.1039/P19840002425 |
1,2-Thiazines and related heterocycles. Part 2. Synthesis and characterisation of the cycloadducts of N-sulphinylanilines and 1,4-epoxy-1,4-dihydro-naphthalenes. Derivatives of 5H-6-thia-5-azabenz[a]anthracene 6-oxide Peter Hanson and Thomas W. Stone pg 2429; DOI: 10.1039/P19840002429 |
Peptide-bond formation, chemoselective acylation of amino acids, and crosslinking reaction between amino acids utilizing a functional five-membered heterocycle, 1,3-thiazolidine-2-thione Yoshimitsu Nagao Tadayo Miyasaka Kaoru Seno Eiichi Fujita Daisuke Shibata and Etsushiro Doi pg 2439; DOI: 10.1039/P19840002439 |
Synthesis of 2,4-dioxo-, 2-oxo-4-thioxo-, 4-oxo-, and 4-thioxo-pyrimidine-5-carbonitriles Francisco J. Cuadrado Miguel A. Pérez and José L. Soto pg 2447; DOI: 10.1039/P19840002447 |
Preparation of some polymer-supported crown ethers and their use as phase-transfer catalysts Philip Hodge Ezzatollah Khoshdel and Janette Waterhouse pg 2451; DOI: 10.1039/P19840002451 |
Preparation, pyrolysis, and photolysis of three sterically crowded alkenes, 3,3,3,3,5,5,5,5-octamethyl-3,3,5,5-tetrahydro-4,4-bi(4H-pyrazolylidene) 2,2,4,4-tetramethyl-3-(3,3,5,5-tetramethyl-3,5-dihydro-4H-pyrazol-4-ylidene)-thietane 1,1-dioxide and 2,2,2,2,4,4,4,4-octamethyl-3,3-bithietanylidene 1,1,11-tetraoxide, potential precursors to the octamethyltetramethyleneethane (TME) biradical Richard J. Bushby Stephen Mann and Malini V. Jesudason pg 2457; DOI: 10.1039/P19840002457 |
Umpolung of o-phenylenediamines by conversion into isobenzimidazole. An expedient approach to heterocycles with nucleophilic substituents Kathryn E. Davies George E. Domany Mahmoud Farhat John A. L. Herbert Alan M. Jefferson Maria de los A. Guttierrez Martin and Hans Suschitzky pg 2465; DOI: 10.1039/P19840002465 |
Use of chloroalkenylamines for the synthesis of 1-azabicyclo[3.3.0]octane and 1-azabicyclo[4.3.0]nonane derivatives Alistair W. Lochead George R. Proctor and Michael P. L. Caton pg 2477; DOI: 10.1039/P19840002477 |
Pyridazine-4,5-dicarboxylic anhydride: versatile synthon for the preparation of 1,3,7,8-tetra-azaspiro[4.5]decane derivatives with nitrogen 1,3-binucleophiles Stefano Chimichi Rodolfo Nesi and Martino Neri pg 2491; DOI: 10.1039/P19840002491 |
Photochemical reactions of phenylacetylenes with ethylene trithiocarbonate. Synthesis of phenyl-substituted 2-thioxo-1,3-dithioles Shuzo Yamada Norihisa Mino Noboru Nakayama and Mamoru Ohashi pg 2497; DOI: 10.1039/P19840002497 |
Methyl 4-oxothiolane-3-carboxylate and methyl 2-methyl-4-oxothiolane-3-carboxylate anions as synthetic equivalents of -acrylate and -crotonate anions. Formal synthesis of integerrinecic acid Pier Giovanni Baraldi Mario Guarneri Gian Pierp Pollini Daniele Simoni Achilla Barco and Simonetta Benetti pg 2501; DOI: 10.1039/P19840002501 |
A new epoxidation reaction: base-catalysed stereospecific epoxidation with -azohydroperoxides Takahiro Tezuka and Masaaki Iwaki pg 2507; DOI: 10.1039/P19840002507 |
The structures of pseudoanisatin and its novel base-catalysed rearrangement product Isao Kouno Hiroshi Irie and Nobusuke Kawano pg 2511; DOI: 10.1039/P19840002511 |
Some approaches to the synthesis of kainic acid Suren Husinec Alexander E. A. Porter James S. Roberts and Calum H. Strachan pg 2517; DOI: 10.1039/P19840002517 |
A kinetic template effect in the metal ion-catalysed reactions of o-bromodiarylazo compounds with tertiary phosphines. 13C n.m.r. and X-ray structural studies of o-phosphoniodiarylazo derivatives. David W. Allen Ian W. Nowell Lorraine A. March and Brian F. Taylor pg 2523; DOI: 10.1039/P19840002523 |
1-Benzazepines. Novel ring transformations occurring during the reactions of 5-methyl- and 5-phenyl-1,3-dihydro-2H-1-benzazepin-2-ones with phosphoryl chloride Michael B. Stringer Vincenzo Candeloro John H. Bowie Rolf H. Prager Lutz M. Engelhardt and Allan H. White pg 2529; DOI: 10.1039/P19840002529 |
New features in the intramolecular capture of nitrile imines by the sulphide function Luca Bruché Luisa Garanti and Gaetano Zecchi pg 2535; DOI: 10.1039/P19840002535 |
Pyrrole studies. Part 28. The effect of steric hindrance upon the reaction of 2-vinylpyrroles with dimethyl acetylenedicarboxylate R. Alan Jones Teresa Aznar Saliente and José Sepúlveda Arques pg 2541; DOI: 10.1039/P19840002541 |
Syntheses and properties of the mesoionic analogues of sesquifulvalene possessing a 1,3-diphenyltetrazolium ring Shuki Araki and Yasuo Butsugan pg 2545; DOI: 10.1039/P19840002545 |
Pummerer rearrangements using chlorotrimethylsilane Simon Lane Stephen J. Quick and Richard J. K. Taylor pg 2549; DOI: 10.1039/P19840002549 |
Heterocyclic compounds with bridgehead nitrogen atoms. Part 10. Synthesis in the pyrrolo[2,1,5-de]quinolizine series ([2.3.3]cyclazinones and [2.3.3]cyclazinylium salts) starting from quinolizines David Farquhar Thomas T. Gough Derek Leaver James F. Miller James W. Dick and Michael A. Jessep pg 2553; DOI: 10.1039/P19840002553 |
Synthesis of biflavonoids in which the flavan units are linked through oxygen from C-2 to C-3 or C-4 Ben R. Brown Ian A. Stuart and A. William R. Tyrrell pg 2563; DOI: 10.1039/P19840002563 |
Naturally occurring dibenzofurans. Part7. The synthesis of -rhodomyrtoxin Christopher F. Carvalho and Melvyn V. Sargent pg 2573; DOI: 10.1039/P19840002573 |
Access to phenolic fungal metabolites via the acid-catalysed Claisen rearrangement. The total synthesis of ()-mellein, aurocitrin, and 5,6-dihydroaurocitrin By Laurence M. Harwood pg 2577; DOI: 10.1039/P19840002577 |
Photolysis and thermolysis of 3-azidonoradamantane. Anti-bredt imines, 2-aza-adamant-1-ene, and 4-azaprotoadamant-3-ene Mikolaj Jawdosiuk and Peter Kovacic pg 2583; DOI: 10.1039/P19840002583 |
Thermolysis of aryl azides in phenyl isocyanate Dalpat I. Patel and Robert K. Smalley pg 2587; DOI: 10.1039/P19840002587 |
Use of piperidine-1-sulphenyl chloride as a sulphur-transfer reagent in reactions with diamines: the preparation of sulphur–nitrogen heterocycles Martin R. Bryce pg 2591; DOI: 10.1039/P19840002591 |
Synthesis of the 11-(hydrogen succinate) and 11-(-D-glucopyranosiduronic acid) derivative of estra-1,3,5(10)-triene-3,11,17-triol David N. Kirk and Christopher J. Slade pg 2595; DOI: 10.1039/P19840002595 |
Dihydroimidazoles in synthesis: C-acylation of lithiodihydroimidazoles Michael W. Anderson Michael J. Begley Raymond C. F. Jones and John Saunders pg 2599; DOI: 10.1039/P19840002599 |
Diborane reduction of penicillins: preparation of 7-deoxopenicillanic acid Peter G. Sammes Steven Smith and Geoffrey T. Woolley pg 2603; DOI: 10.1039/P19840002603 |
The preparation of 3H-1,2-diazepine 2-oxides and their rearrangement to give 3-alkenyl-3H-pyrazole 2-oxides Carl B. Argo Ian R. Robertson and John T. Sharp pg 2611; DOI: 10.1039/P19840002611 |
Synthesis and characterisation of bis[(methylthio)carbonyl]polysulphanes Andrew W. Mott and George Barany pg 2615; DOI: 10.1039/P19840002615 |
A simple and general route to aryl iodides from arenes Jose Barluenga Pedro J. Campos José M. González and Gregorio Asensio pg 2623; DOI: 10.1039/P19840002623 |
Mechanism and stereochemistry of the porphobilinogen deaminase and protoporphyrinogen IX oxidase reactions: stereospecific manipulation of hydrogen atoms at the four methylene bridges during the biosynthesis of haem. Christopher Jones Peter M. Jordan and Muhammad Akhtar pg 2625; DOI: 10.1039/P19840002625 |
Reaction of aryl aldehydes with thiocyanates in the presence of tributylphosphine Masataka Yokoyama Hiroko Ohteki Masahiko Kurauchi Kazuko Hoshi Eizaburo Yanagisawa Ariko Suzuki and Tsuneo Imamoto pg 2635; DOI: 10.1039/P19840002635 |
Thermal cycloaddition reactions of thiocarbonyl compounds. Part 2. 1,3-dipolar cycloaddition reactions of adamantanethione with nitrile oxides, nitrilimines, and diazoalkanes Tomonori Katada Shoji Eguchi and Tadashi Sasaki pg 2641; DOI: 10.1039/P19840002641 |
Thermal cycloaddition reactions of thiocarbonyl compounds. Part 3. A novel [4 + 2] cycloaddition reaction of thiocarbonyl compounds with o-quinone methanides Tomonori Katada Shoji Eguchi Toshiyuki Esaki and Tadashi Sasaki pg 2649; DOI: 10.1039/P19840002649 |
Unusual Friedel-Crafts reactions. Part 8. Synthesis of 2-hydroxyarylglyoxylic acids via ortho-specific oxaloylation of phenols with oxalyl chloride Franca Bigi Giovanni Casiraghi Giuseppe Casnati and Giovanni Sartori pg 2655; DOI: 10.1039/P19840002655 |
Regioselective dihydroarene oxide formation during ortho-hydroxylation of halogenobenzenes by fungi Barbara J. Auret Suresh K. Balani Derek R. Boyd Ruth M. E. Greene and Glenn A. Berchtold pg 2659; DOI: 10.1039/P19840002659 |
Characterization of L-methionine in a peptide -helix by far-infrared spectroscopy. Synthesis and examination of sequential polypeptides containing L-methionine Ryoichi Katakai and Yasuko Iizuka pg 2665; DOI: 10.1039/P19840002665 |
Bredt's rule. Part 6. The synthesis of 5-phenyl-1-azabicyclo[3.3.1 ]nonan-2-one,a bridgehead amide George L. Buchanan pg 2669; DOI: 10.1039/P19840002669 |
Photorearrangement studies of 3-heteroaryl-substituted cyclopropenes Albert Padwa Ugo Chiacchio Anna Compagnini Antonino Corsaro and Giovanni Purrello pg 2671; DOI: 10.1039/P19840002671 |
Allence. Part 43. A novel synthesis of pyrimidines of potential pharmaceutical interest from allenic nitriles Stephen R. Landor Phyllis D. Landor and V. E. Williams pg 2677; DOI: 10.1039/P19840002677 |
Water-soluble macrocyclic paddlanes and propellane as a new class of host molecules Yoshito Tobe Hisashi Fujita Itsuyo Wakaki Kaoru Terashima Kazuya Kobiro Kiyomi Kakiuchi and Yoshinobu Odaira pg 2681; DOI: 10.1039/P19840002681 |
-Substituted organoalkaline tri- and tetra-anions; preparation, stability, and reactivity José Barluenga Francisco J. Fañanás Jorge Villamaña and Miguel Yus pg 2685; DOI: 10.1039/P19840002685 |
Use of 1-[(methylthio)thiocarbonylmethyl]pyridinium iodide as the starting material for the synthesis of 1-heteroarylmethylpyridinium salts Julio Alvarez-Builla Felipe Sanchez-Trillo and Gloria Quintanilla pg 2693; DOI: 10.1039/P19840002693 |
Mechanistic study of the thermal acid-catalysed rearrangement of trans-methyl chrysanthemate to lavandulyl derivatives Zeev Goldschmidt Bernard Crammer and Raphael Ikan pg 2697; DOI: 10.1039/P19840002697 |
Synthesis and characterisation of some new 2,6-disubstituted thiazolo-[3,2-b][1,2,4]triazine-3,7-diones Libero Italo Giannola Gaetano Giammona Salvatore Palazzo and Liliana Lamartina pg 2707; DOI: 10.1039/P19840002707 |
Reactions with methyl 3-hydroxythiophene-2-carboxylate. Part 2. A new route to mono- and di-alkyl ethers of thiotetronic and -halogenothiotetronic acids Carlos Corral and Jaime Lissavetzky pg 2711; DOI: 10.1039/P19840002711 |
Selective ortho-methylthiomethylation of phenols with dimethyl sulphoxide and thionyl chloride Kikumasa Sato Seiichi Inoue Kimio Ozawa and Michiko Tazaki pg 2715; DOI: 10.1039/P19840002715 |
Stepwise oxidation of Z-threonyl- and Z-seryl-glycine esters and related compounds Virgilio Giormani Fernando Filira and Ferruccio D'Angeli pg 2721; DOI: 10.1039/P19840002721 |
Synthetic studies relevant to biosynthetic research on vitamin B12. Part 1. Syntheses of C-methylated chlorins based on 1-pyrrolines (3,4-dihydropyrroles) Alan R. Battersby Christopher J. R. Fookes and Roger J. Snow pg 2725; DOI: 10.1039/P19840002725 |
Synthetic studies relevant to biosynthetic research on vitamin B12. Part 2. Syntheses of C-methylated chlorins via lactams Alan R. Battersby Christopher J. R. Fookes and Roger J. Snow pg 2733; DOI: 10.1039/P19840002733 |
Synthetic studies relevant to biosynthetic research on vitamin B. Part 3. An approach to isobacteriochlorins via nitrones Alan R. Battersby and Lawrence A. Reiter pg 2743; DOI: 10.1039/P19840002743 |
Studies in terpenoid biosynthesis. Part 30. The acetate and mevalonate labelling patterns of the diterpenoid, aphidicolin Mark J. Ackland James R. Hanson and Arnold H. Ratcliffe pg 2751; DOI: 10.1039/P19840002751 |
The structure of thiobiscephalosporolide A, A dimeric pentaketide macrolide from Cephalosporium aphidicola Mark J. Ackland James R. Hanson Peter B. Hitchcock Richard P. Mabelis and Arnold H. Ratcliffe pg 2755; DOI: 10.1039/P19840002755 |
A short synthesis via a common intermediate of N1- and N8-monoacylspermidine conjugates Rajeswari Sundaramoorthi Jean-Louis Fourrey and Bhupesh C. Das pg 2759; DOI: 10.1039/P19840002759 |
Triazines and related products. Part 28. Conversion of 3-aryl-1-(2-cyanophenyl)triazenes into 3-arylquinazolin-4(3H)-ones with formamide Ghouse Unissa Baig and Malcolm F. G. Stevens pg 2765; DOI: 10.1039/P19840002765 |
Synthesis of isoflavanoid oligomers using a pterocarpan as inceptive electrophile Barend C. B. Bezuidenhoudt Edward V. Brandt and David G. Roux pg 2767; DOI: 10.1039/P19840002767 |
Termal rearrangement of 1-alkyl-3,6-diaryl-1,4-dihydro-s-tetrazines to 1-alkylamino-3,5-diaryl-1,2,4-triazoles Daniel Hunter and Douglas G. Neilson pg 2779; DOI: 10.1039/P19840002779 |
Total synthesis of analogues of the -lactam antibiotics. Part 2. Isopenam-3-carboxylates and their 2,2-dioxides Peter H. Crackett Chandra M. Pant and Richard J. Stoodley pg 2785; DOI: 10.1039/P19840002785 |
Purines, pyrimidines, and imidazoles. Part 60. Some oxazolo[3,2-a]pyrimidines and a novel conversion of a cyanouracil into a barbituric acid derivative Rosario Alonso Gordon Shaw and David Wright pg 2795; DOI: 10.1039/P19840002795 |
Protection of primary amines as N-substituted 2,5-dimethylpyrroles Stephen P. Bruekelman (Miss) Susan E. Leach G. Denis Meakins and Malcolm D. Tirel pg 2801; DOI: 10.1039/P19840002801 |
Biosynthesis of L-2,3-diaminopropanoic acid Julianus L. van der Baan Joachim W. F. K. Barnick and Friedrich Bickelhaupt pg 2809; DOI: 10.1039/P19840002809 |
Studies of chromenes. Part 4. Oxidation of hexahydro-5H-chromeno[3,4-c]-pyridazines and conformational isomerism in tetra-and hexa-hydro-N,N-dialkoxycarbonyl-5H-chromeno[3,4-c]pyridazines Panayiotis Anastasis Philip E. Brown and Wafa Y. Marcus pg 2815; DOI: 10.1039/P19840002815 |
The reaction of benzyne with imines Colin W. G. Fishwick Ramesh C. Gupta and Richard C. Storr pg 2827; DOI: 10.1039/P19840002827 |
Isoflavonoid biosynthesis: concerning the aryl migration Hakim A. M. Al-Ani and Paul M. Dewick pg 2831; DOI: 10.1039/P19840002831 |
The generation and synthetic utility of dianions derived from benzofurancarboxylic acids Cheryl D. Buttery David W. Knight and Andrew P. Nott pg 2839; DOI: 10.1039/P19840002839 |
1-Aminoalkylphosphonous acids. Part 1. Isosteres of the protein amino acids E. Keith Baylis Colin D. Campbell and John G. Dingwall pg 2845; DOI: 10.1039/P19840002845 |
Reaction of aromatic aldehydes with 1,2-dibenzylhydrazine Patrick N. Anderson and John T. Sharp pg 2855; DOI: 10.1039/P19840002855 |
An unusual gibberellin transannular ketol Mark K. Baynham and James R. Hanson pg 2859; DOI: 10.1039/P19840002859 |
Methyl vs. methylene condensation of aromatic aldehydes with 1,1,1-trifluoroacetylacetone Aviv Gazit and Zvi Rappoport pg 2863; DOI: 10.1039/P19840002863 |
Reactions of 4-fluoren-9-ylidene-2-methylpent-2-ene and 2-fluoren-9-yl-2- methylpentan-4-one Harry G. Heller and (Mrs) Gillian A. Jenkins pg 2871; DOI: 10.1039/P19840002871 |
Photoreactions of photochromic 1-(2,5-dimethyl-3-furyl)-1-fluoren-9-ylidene-ethane and related compounds Harry G. Heller and (Mrs) Gillian A. Jenkins pg 2877; DOI: 10.1039/P19840002877 |
Base-catalysed double-bond isomerizations of cannabinoids: structural and stereochemical aspects Morris Srebnik Naphtali Lander Aviva Breuer and Raphael Mechoulam pg 2881; DOI: 10.1039/P19840002881 |
Asymmetric synthesis using chirally modified borohydrides. Part 2. Enantioselective reduction of ketones with polymeric (S)-prolinol–borane reagent Shinichi Itsuno Koichi Ito Akira Hirao and Seiichi Nakahama pg 2887; DOI: 10.1039/P19840002887 |
[2,3] Fused indoles. Synthesis of -carbolines and azepino[4,5-b]indoles from 3-(2-alkylindol-3-yl)-2-azidoacrylates1 Christopher J. Moody and John G. Ward pg 2895; DOI: 10.1039/P19840002895 |
[2,3] Fused indoles. Part 2. Synthesis of 1,8-dihydropyrrolo[2,3-b]indoles, and photochemical rearrangement of their 1-allyl derivatives Christopher J. Moody and John G. Ward pg 2903; DOI: 10.1039/P19840002903 |
Photocyclisation of enamides. Part 22. Syntheses of the despyrrole analogues of some ergot alkaloids including methyl lysergate and isofumigaclavine A2 Ichiya Ninomiya Chiyomi Hashimoto Toshiko Kiguchi and Takeaki Naito pg 2911; DOI: 10.1039/P19840002911 |
The biosynthesis of rubrofusarin, a polyketide naphthopyrone from Fusarium culmorum: 13C n.m.r. assignments and incorporation of 13C- and 2H-labelled acetates Finian J. Leeper and James Staunton pg 2919; DOI: 10.1039/P19840002919 |
Reductive cleavage of the nitrogen–nitrogen bond in hydrazine derivatives John M. Mellor and Neil M. Smith pg 2927; DOI: 10.1039/P19840002927 |
Reactions of S-alkyl-N,N-disubstituted thioamide salts. Part 4. Sulphenamidine derivatives Frank Stansfield pg 2933; DOI: 10.1039/P19840002933 |
A 2H n.m.r. study of the dienol–benzene and related steroid aromatization reactions James R. Hanson Paul B. Reese and Ian H. Sadler pg 2937; DOI: 10.1039/P19840002937 |
Allylic acetoxylation of 5-steroids at C-4 James R. Hanson Paul B. Reese and Harry J. Wadsworth pg 2941; DOI: 10.1039/P19840002941 |
Structure reinvestigation of conyzorigun, a new chromone from Ageratum conyzoides Ashok V. Vyas and Newand B. Mulchandani pg 2945; DOI: 10.1039/P19840002945 |
Corrigenda Michèle Blanc-Muesser Jacques Defaye Hugues Driguez Guy Marchis-Mouren Christian Seigner Maryvonne Frostin-Rio Danièle Pujol Claude Bied-Charreton Martine Perrée-Fauvet and Alain Gaudemer pg 2949; DOI: 10.1039/P19840002949 |